An Giang info: Youtube daily report Feb 10 2019

Hi Friends welcome to C4E Wrestling News How WWE Upset Dean Ambrose During Contract Talks

Dean Ambrose is leaving WWE when his contract is up in April It is said that AEW will have

an interest in bringing Ambrose in when he is a free agent However the idea of Ambrose

using AEW to get more money out of WWE was not one he appreciated Ambrose is in good

financial shape Therefore he wasn't staying with WWE for the money In fact he resents

those who seem to be sticking around just for the paycheck Dean Ambrose's WWE exit

was due to frustration with creative Ambrose was already in a pretty frustrated mood because

his answer didn't change but there was still a series of meetings he had to endure over

the Royal Rumble weekend When the idea was brought up that Ambrose was just leveraging

AEW for a bigger paycheck from WWE the idea only upset him more Some within the company

believed this line of thinking In the meantime Ambrose is still a WWE Superstar and will

work all of the dates that WWE book him for The company even booked him against Nia Jax

later next month in an intergender match WWE said that the door is open for Ambrose's

return You never know if WWE might try something else to get him to stay in the meantime Friends

what are your thought about this Have your say in the comments section below

For more infomation >> How WWE Upset Dean Ambrose During Contract Talks - Duration: 1:44.

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WWS S6 J Jeffrey Messerole "Henrietta, Queen of the Highway" - Duration: 5:19.

♪

You left home when you were barely 16 years of age,

crashing on couches and taking up floor space

But you promised yourself

you'd never go back home again

♪

When he wasn't stoned your dad was drunk and mean,

and you had the kind of mother looking under rugs

to sweep so it was easier to run

than to sit and face the pain

♪

Henrietta

Queen of the Highway

♪

You turned 21 inside a bottle of cheap gin

You traded it for a loosey and a little bit of sin

It's easier to compromise yourself

when you need a god damn drink

♪

Now the line between right and wrong has become razor thin

So what if all you gotta do is show a little skin

You're headed down a road to a place

you never thought you'd sink

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

You can spot your targets from a mile down the road,

you know them long haul drivers get more for carrying their load

So you'll rob them beneath the lights of the lot

pray you don't have to use your knife

♪

Well it wouldn't be the first time that violence was your will,

that's why you left Nebraska said it was kill or be killed.

Now the law out there has got you

running for your life

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

Henrietta

♪

Queen of the

Highway

[Applause]

For more infomation >> WWS S6 J Jeffrey Messerole "Henrietta, Queen of the Highway" - Duration: 5:19.

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WWS S6 - Episode 16 - WEBCAST - Duration: 23:32.

From The Last Stop Studios

In Sioux Falls, South Dakota

You're watching The White Wall Sessions

Tonight on The White Wall

Andrea von Kampen

J Jeffrey Messerole and the Stone Horses

The Gentlemen's Anti-Temperance League

Ilika Ward

and The Working Poor

The White Wall Sessions is presented

by Last Stop CD Shop

Something for everyone in the family

at your one stop entertainment shop

The White Wall Sessions is sponsored by

Workplace I.T. Management

The Evolved Approach to I.T.

Bell Incorporated

the face of packaging innovation

and Screenflair

Protect In Style

Ladies and Gentlemen

The White Wall Sessions

Andrea: Plug this in

I learned that lesson

[Background Chatter]

Andrea: Definitely

[Guitar Warms Up with Background Chatter]

Andrea: Cool this song is called "Julia"

♪

Julia lays in the sunshine

and waits

♪

Out by the water

on the bay

♪

And the sun goes down and the sun goes down

Where is her lover?

The day is breaking over the water

♪

Julia moves to the city

to find

A new set of memories

clear her mind

♪

And the sun goes down and the sun goes down

She won't find another

Julia is hung up

on her lover

♪

Hmmm

♪

Hmmm

♪

And oh,

the time passes slowly

And oh,

God she's so lonely

And oh,

they all say

That time

time heals the sting

♪

Julia skips down the sidewalk

its Spring

Spring in the city

blooming trees

And she walks alone and she laughs alone

The lady is lovely

Julia won't wait

for anybody.

♪

[Applause]

[Applause] - Andrea: Thank you.

[Applause]

[Band Warms Up with Background Chatter]

J Jeffrey: I jinked myself

[Band Warms Up with Background Chatter]

This song is called "Henrietta, Queen of the Highway"

[Background Chatter]

♪

You left home when you were barely 16 years of age,

crashing on couches and taking up floor space

But you promised yourself

you'd never go back home again

♪

When he wasn't stoned your dad was drunk and mean,

and you had the kind of mother looking under rugs

to sweep so it was easier to run

than to sit and face the pain

♪

Henrietta

Queen of the Highway

♪

You turned 21 inside a bottle of cheap gin

You traded it for a loosey and a little bit of sin

It's easier to compromise yourself

when you need a god damn drink

♪

Now the line between right and wrong has become razor thin

So what if all you gotta do is show a little skin

You're headed down a road to a place

you never thought you'd sink

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

You can spot your targets from a mile down the road,

you know them long haul drivers get more for carrying their load

So you'll rob them beneath the lights of the lot

pray you don't have to use your knife

♪

Well it wouldn't be the first time that violence was your will,

that's why you left Nebraska said it was kill or be killed.

Now the law out there has got you

running for your life

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

Henrietta

Queen of the Highway

♪

Henrietta

♪

Queen of the

Highway

[Applause]

Announcer: Promotional items

for The White Wall Sessions

provided exclusively by Minuteman Press

Downtown Sioux Falls.

Mention The White Wall Sessions for a 10% discount.

[Commercial Break]

[Band Warms Up with Background Chatter]

♪

Cold at home

Wake up sweating on a winter's day

Half a mind to lay back down

And let the world just drift away

Hold me close

A summertime embrace

The sleep won't last

But at least we've got this place

♪

Yes I know that there's snow outside

But the truth has never warmed me right

We'll wake up soon and look out the window

We just need another moment face-to-face

♪

So keep me warm

Hold the fever dreams at bay

We'll huddle close in nature's clothes

And plan for a brighter day

We'll whisper prayers

For killing time

While better folks

Are struggling with the ice

♪

It's almost time to wake up my dear

The snow won't wait for us to wake

Before it melts away.

It's almost time to wake up my dear

The snow won't wait for us to wake

Before it melts away.

♪

[Applause]

[Applause] - Thanks everybody. Thank you.

[Guitars Warm Up with Background Chatter]

Jake: This one's called "Leo and Leonas"

♪

Leo and Leonas

sits on a corner

outside Lacrosse, Wisconsin

in the middle of nowhere

If you don't know where you're going

You'll probably think you're lost

it just might be the best place these tired feet have crossed

♪

We went in after sunset

And tuned up our guitars

stepped out to have a smoke

And look up at the stars

Like a place in a dream

Of an old western bar

Somebody pinch me don't know how lucky we are

♪

How lucky we are

To say that we've played

In front of these people

On top of this stage

We're the luckiest men in the world

on that day

♪

Doing the thing that we love so much in this place

♪

I only met him once or twice and damn he was swell

He gave himself to music before he fell

I'm afraid this place won't be the same

Not even the smell

This lonely road's halfway to heaven but also halfway to hell

♪

How lucky we are

To say that we've played

In front of these people

On top of this stage

We're the luckiest men in the world

on that day

♪

Doing the thing that we love so much in this place

♪

Leo and Leona's

sits on a corner

outside Lacrosse, Wisconsin

in the middle of nowhere

If you don't know where you're going

You'll probably think you're lost

it just might be the best place these tired feet have crossed

it just might be the best place these tired feet

♪

tired feet have crossed

♪

[Applause] - Joel: Thanks guys. Jake: Thanks a lot.

[Applause]

[Guitars Warm Up with Background Chatter]

[Commercial Break]

[Band Warms Up with Background Chatter]

♪ - 1, 2, 3, 4

♪

Pass me the note from the all night dancer

Hear the ghost and you'll hear the answer

Hear it all, hear it all

She's dancing for the troops

and the boys in the band

Woo Hoo

♪

Well he can howl on cue, won't you see me tonight

He can't see, but he can see the light

He don't like it,

he don't like it

You can see him now with the boys in the band

Woo Hoo

♪

He sits there prone to the one night stand

Doesn't even know of the crap I'm in

Give it now,

give it to me now

You can feel his fear with

the boys in the band

Woo Hoo

♪

[Applause]

[Band Warms Up with Background Chatter]

Closed Captions Provided by The Dub Hut.

For more infomation >> WWS S6 - Episode 16 - WEBCAST - Duration: 23:32.

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Red Flash make it 5 in a row - Duration: 0:49.

For more infomation >> Red Flash make it 5 in a row - Duration: 0:49.

-------------------------------------------

Constitutional isomers of C4H8O2 | Carboxylic acid & Ester - Dr K - Duration: 4:26.

We're gonna draw out all possible carboxylic acid and ester isomers for

C4H8O2 in this video. Before we begin, how many isomers do you think we will get?

Stay tuned until the end to compare notes. Let's begin. Quick recap.

Carboxylic acid has a carboxyl functional group which is C double bond O

connected to OH, whereas ester is C double bond Oo connected to OC.

The difference between carboxylic acid and ester is carboxylic acid has a H

connected to that O, whereas ester has a C connected to O. Another thing to note

is that for carboxylic acid that COOH group which is called carboxyl group,

it's always a carbon number 1, so, let's start with carboxylic acid. Since we have

four carbons, let's place the COOH group at the beginning and then we will add in

the remaining carbons in a row like this. That's our first carboxylic acid isomer

having a 4 carbon chain. 4 carbon chain because we have 4 carbon straight

in a row. Now instead of placing all 4 carbons in a row we can actually place 3

carbons in a row and then stick the fourth carbon like this on carbon 2.

That will give us another isomer. What if we were to stick that extra

carbon on carbon 3? It's actually the same as our first structure. Notice it's

a 4 carbon chain, so, it looks like we are done drawing the carboxylic acids.

Let's fill in with the hydrogens and here we go the two structures for carboxylic acid.

Let's move on to ester. For ester, the functional group is COOC,

so, let's start by placing that at the beginning. We've already used up 2

carbon and 2 oxygens so far, so, for the remaining two carbons we are going to

place them after that COOC group like this so that will give us a

1+3 combo. Retaining the 1 carbon at carbonyl group, let's shorten the 3

carbon to 2 carbon and we'll place the third carbon like this.

That will give us another isomer for ester. Now, since we can't shorten the

chain after O anymore, let's move on to two carbons on the carbonyl group like this.

So this gives us a 2+2 combo. Looks like we can't shorten the chain, either

chain anymore, so, let's move on to 3 carbon on the carbonyl group and this

will give us a 3+1 combo. Since we can't shorten either chain and

we need at least one carbon after that oxygen, because we want to draw ester, so,

it looks like we are done. So, we fill up these structures with remaining

hydrogens and it will give us these. Keep in mind that each carbon makes four

bonds, so, make sure that you check to make sure that every structure has 8

hydrogens, no more and no less. Quick recap on how we drew all 4 isomers for ester.

We started with 1 carbon on the carbonyl group and then we placed 3

carbon of the oxygen. Since we can shorten the three carbon chain to two

carbon, we then drew the second isomer with the two carbon and extra carbon

sticking on C1. Since we've exhausted this combo, we then move on to 2 carbon

on the carbonyl group. Because we can't shorten the chain anymore we then move

on to 3 carbon on the carbonyl group. We can't have 4 carbon on the carbonyl group

for this formula because that would have given us a carboxylic acid instead of

esters. So using this systematic way, we know that we have drawn out all possible

isomers for ester. To recap, we have drawn out a total of 2 carboxylic acids and

4 esters for C4H8O2. A quick disclaimer though the numbering that I

used in these structures, they are not meant for naming, it's just to help us see

how many carbons that we have on each side of the structure, so, don't get

confused. If you're interested in drawing other isomers aside from carboxylic acid

and esters for C4H8O2, to let me know in the comments and I'll post a video for it.

Hope the video was helpful somehow. Do subscribe and thanks for watching!

An Giang info

Saturday, February 9, 2019

Youtube daily report Feb 10 2019

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