Youtube daily report Feb 10 2018

I'm going to start again.

Let's track this from the beginning.

('90s POP SONG PLAYING)

(SINGING) ♪ Yo listen up here's a story

♪ About a little guy that lives in a blue world

♪ And all day and all night and everything he sees

♪ Is just blue like him inside and outside

♪ Blue is his house with a blue little window

♪ And a blue Corvette

♪ And everything is blue for him and himself

♪ And everybody around

♪ 'Cause he ain't got nobody... ♪

(PEOPLE LAUGHING) (INDISTINCT CONVERSATIONS)

(HONKS) (CHUCKLING)

Half hour till the ball drops.

- Hey, do you wanna... - Tony Stark?

- Great speech, man! HAPPY: - I got you, pal.

I gave a speech? How was it?

- Edifying. - Unintelligible.

- Really? - Mmm-hmm.

It's my favourite kind. A winning combo.

- Where are we going? - Uh, to town, on each other.

Probably back in your room

because I also want to see your research.

Okay, you can see my research,

but that's... I'm not gonna show you my "town."

Mr Stark.

Ho Yinsen.

Ah, I finally met a man called "Ho."

(CHUCKLES HUMOURLESSLY) - Come here.

I would like to introduce you to our guest, Dr Wu.

- Oh, this guy. Hey. - Mr Stark.

(GREETS IN MANDARIN) - You're a heart doctor.

She's going to need a cardiologist after I...

(HONKING)

- Bye. - Perhaps another time?

TONY: It started in Bern, Switzerland. 1999.

(PEOPLE YELLING INDISTINCTLY)

- The old days. KILLIAN: - Mr Stark!

TONY: I never thought they would come back to bite me.

Why would they?

Oh, wow! Hey, Tony!

Aldrich Killian. (STUTTERING) I'm a big fan of your work.

- My work? - Who isn't? He means me.

Well, of course, but, Ms Hansen,

my organisation's been tracking your research since year two of MIT.

TONY: Yeah, we're full.

Oh, wow, he made it. He made the cut.

What floor you going to, pal?

Well, now, that is an appropriate question.

The ground floor, actually,

of a proposal I'm putting together myself.

It's a privately funded think tank called Advanced Idea Mechanics.

- Uh... - She'll take both.

One to throw away and one to not call.

"Advanced Idea Mechanics" or "AIM," for short. Do you get it?

- I see that, because it's on your T-shirt. - Aw!

Ladies, follow the mullet. Ladies first.

Thank you, I'll call you.

(WOMEN TALKING EXCITEDLY)

I'm titillated by the notion of working with you.

- Yeah? - I'll ditch these clowns.

I'll see you up on the roof in five minutes.

Just gonna try and get my beak wet real quick.

You know what I'm talking about?

I'll see you up there.

TONY: Damn betcha.

Come on! I thought that was just a theory.

Well, it was.

If I'm right, we can access the area of the brain

- that governs repair... TONY: - Wow.

MAYA: ...and chemically recode it.

That's incredible. Essentially, you're hacking into the genetic...

BOTH: ...operating system...

- ...of a living organism. - Exactly.

- Yes. - Wow.

Is that... Can you...

- What? - Can you not touch my plant?

It's not... She doesn't like it. She prefers...

She's not like the others. Come on. Let's go in the bedroom.

- Happy... - Hmm. That's cute...

Leave her ficus alone.

Because... And, no, seriously, don't.

TONY: And you're starting with plants.

MAYA: For now, yeah. TONY: Huh.

I'm calling it EXTREMIS.

- Well, it's... BOTH: - Human application.

Exactly, exactly.

- Dendritic revitalisation. - It's revolutionary.

- Disease prevention... - Change the world.

...even limb regrowth.

You're the most gifted woman I've ever met.

Wow.

- In Switzerland. - Hmm. That's better.

- Aw, you're seeing things. - This week.

(CHUCKLES) You almost bought it, didn't you?

(EXPLOSION) (GLASS SHATTERING)

This is what I'm talking about, the glitch.

Have you checked the telomerase algorithm?

- The what? HAPPY: - Down!

Stay down! Stay down, boss.

- We're good. - Stay down.

You... You're... You're right on me. I made it.

What the hell was that?

(PEOPLE OUTSIDE COUNTING DOWN)

- What was that? MAYA: - It's a glitch in my work. It's...

She was just talking about it. Glitches happen.

HAPPY: It's not Y2K.

(PEOPLE OUTSIDE CHEERING) - Hey! Happy New Year!

HAPPY: - Happy New Year. MAYA: - Happy New Year.

All right. I'll see you in the morning. Good night.

HAPPY: - You good? - Yeah.

HAPPY: - I'll be right outside. - Okay, cool.

(CHEERING CONTINUES)

TONY: So, why am I telling you this?

Because I had just created demons

and I didn't even know it.

- Yeah, those were good times. (DOOR CLOSES)

Then I moved on.

For more infomation >> Tony Stark Meets Yinsen & Killian | Iron Man 3 (2013) Movie Clip 4K (+Subtitles) - Duration: 4:28.

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Virtual Crime Scene Reconstruction | Iron Man 3 (2013) Movie Clip 4K (+Subtitles) - Duration: 4:25.

- Hi. - Oh!

(CHUCKLES) Do you mind leaving that on?

Sure.

Sunday nights. PBS. Downton Abbey.

That's his show. He thinks it's elegant.

One more thing. Make sure everyone wears their badges.

He's a stickler for that sort of thing.

Plus, my guys won't let anyone in without them.

We're awaiting the arrival of Tony Stark.

We're hoping he'll give us the reaction...

His reaction to the latest attack.

(REPORTERS CLAMOURING) - Mr Stark, hi there.

Our sources are telling us that all signs are pointing to another Mandarin attack.

Anything else you can tell us?

MALE REPORTER: Hey, Mr Stark. When is somebody gonna kill this guy?

I'm just saying.

(CAMERAS CLICKING)

Is that what you want?

Here's a little holiday greeting

I've been wanting to send to the Mandarin.

I just didn't know how to phrase it until now.

My name is Tony Stark and I'm not afraid of you.

I know you're a coward. So I've decided

that you just died, pal.

I'm gonna come get the body.

There's no politics here. It's just good old-fashioned revenge.

There's no Pentagon, it's just you and me.

And on the off chance you're a man, here's my home address.

10880 Malibu Point.

90265.

I'll leave the door unlocked.

That's what you wanted, right?

(REPORTERS GASP)

- Bill me. (REPORTERS CLAMOURING)

JARVIS: I've compiled a Mandarin database for you, sir,

drawn from S.H.I.E.L.D., FBI and CIA intercepts.

Initiating virtual crime scene reconstruction.

Okay. What have we got here?

The name is an ancient Chinese war mantle meaning "advisor to the king."

South American insurgency tactics.

Talks like a Baptist preacher.

There's lots of pageantry going on here. Lots of theatre. Close.

The heat from the blast was in excess of 3, 000 degrees Celsius.

Any subjects within 12.5 yards were vaporised instantly.

No bomb parts found in a three-mile radius of the Chinese Theatre?

No, sir.

Talk to me, Happy.

When is a bomb not a bomb?

Any military victims?

Not according to public record, sir.

Bring up the thermogenic signatures again.

Factor in 3,000 degrees.

The Oracle cloud has completed analysis.

Accessing satellites

and plotting the last 12 months of thermogenic occurrences now.

Take away everywhere that there's been a Mandarin attack.

(SYSTEMS BUZZING)

Nope.

That. Are you sure that's not one of his?

It predates any known Mandarin attack.

The incident was the use of a bomb to assist a suicide.

Bring her around.

The heat signature is remarkably similar.

3,000 degree Celsius.

That's two military guys.

Ever been to Tennessee, Jarvis?

Creating a flight plan for Tennessee.

(DOORBELL RINGS)

Are we still at ding-dong?

- We're supposed to be on total... (BANGING ON TABLE)

...security lockdown.

Come on, I threatened a terrorist. Who is that?

There's only so much I can do, sir,

when you give the world's press your home address.

For more infomation >> Virtual Crime Scene Reconstruction | Iron Man 3 (2013) Movie Clip 4K (+Subtitles) - Duration: 4:25.

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j SALE j

Super Nintendo Entertainment System™: Super NES Classic Edition

The Legend of Zelda Culturefly Collector Mystery Box

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j SALE j

Super Nintendo Entertainment System™ - Super NES Classic Edition

Super Nintendo SNES Culturefly Collector Mystery Box

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« Happy Célibat ! » - épisode 2 - L'anniversaire - Duration: 3:48.

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Alcohol Reaction Deprotonations [Organic Chemistry] Smith 2018 - Duration: 5:42.

In this video I will guide you through a problem in Smith's Organic Chemistry.

I'm Stoddard, founder of studychem, the place for students to turn for higher grades

in ochem.

Let's get started.

In problem 10 we are asked to draw the product of each reaction.

In order to do this problem I highly recommend you follow the sample problem 9.2, which is

to draw the curved arrow reaction mechanisms.

This will help you identify what's negative, what's positive, what's the leaving group,

what's being replaced, and so on.

When you're dealing with sodium hydride, the sodium is positively charged, it's a plus

one cation, hydride is a minus one anion.

Hydride is a base it's going to deprotonate this alcohol.

In order to deprotonate the alcohol, it's really necessary, it's absolutely critical

to draw the oxygen hydrogen bond.

I'm going to draw a little OH there.

Now we can draw the curved arrow reaction mechanism.

The hydride is going to come in and deprotonate the alcohol.

You'll notice how we need to draw this bond so we can show the second arrow here.

And in so doing we can write the products of the reaction.

We're going to have a negative charge on the oxygen.

I won't draw all the other inorganic stuff.

Now we do the same thing down here with NaNH2.

Na is a positive spectator ion with a plus there.

NH2 is negatively charged.

And again in order to draw this acid base reaction, it's really critical to draw that

H out.

If you see this on a homework or an exam or something like that, it's necessary to redraw

the organic molecule so you can see the OH bond out.

Let's go ahead and draw the curved arrow reaction mechanism.

This negative charge here is going to act as a base.

Point it right to the hydrogen.

And this OH bond is going to break and the arrow points to the oxygen.

So the oxygen is going to become negatively charged.

So this makes the alkoxide once again.

So let's draw the five membered ring, draw this branch here and then draw O minus.

Now in this next reaction, we want to draw this hydrogen out.

So let's go ahead and draw this in.

We've got a couple things here.

NaH that's again going to deprotonate the alcohol.

So let's put a positive and negative charge here.

Let's switch to blue pen for the curved arrows.

So this negative charge from the hydride is going to serve as a strong base to deprotonate

the alcohol.

And let's off to the side here sketch what we have here.

We have now this alkoxide and we have 1-bromopropane here.

So, let's draw that out.

And we have this negative charge here which is a strong nucleophile.

Alkoxides attack alkyl halides as we know in the Williamson ether synthesis.

And so we are going to redraw this molecule here with the appropriate number of carbon

atoms.

And attach a propyl group off the oxygen.

So I have oxygen and then I have one two three carbons.

So that's this ether.

Now here this question, well they give us the formula of the product.

And well, what's going on here?

Let's think through the mechanism once again.

We want to draw the OH bond.

We want to go ahead and draw charges so we can figure out what's going to be doing the

deprotonating.

It's the hydride once again.

So this hydride is going to pull a proton off the alcohol and give us an alkoxide.

Now that's not the product, because this formula doesn't have bromine in it.

Now this is a nucleophile.

Negatively charged oxygen atoms are called alkoxides, they're nucleophiles.

And this is an alkyl halide or a halogen which is a good leaving group.

So what can happen here is the negative charge, actually adjacent to itself, attack itself,

kick off the halogen and what you'll get as a product here is the epoxide.

You haven't seen that before, it might be very new to you.

But now that you've seen it, it's more recognizable.

You can form rings from alcohols and alkyl halides.

So, for example, I won't work this out for you, but what product do you think you will

form there?

For more infomation >> Alcohol Reaction Deprotonations [Organic Chemistry] Smith 2018 - Duration: 5:42.

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First Trip To Disney's Animal Kingdom Pandora World Of Avatar: Na'vi River Journey, Banshee, Dessert - Duration: 11:47.

Good morning! Are you excited to go to Anima Kingdom! Yes, it's my one of my favorite parks.

Yeah, it was actually always one of our favorite parks, and now that there's

Pandora, we're really excited to go. It'll be our first time to see it - can't wait!

It's a beautiful park and it's gonna be a nice day.

We survived the bag check!

While we waited for a friend to meet us at Animal Kingdom, we hung out at the

Rainforest Cafe. That's always fun. You can go in and see the fish, and the

animatronics in there, and run under that elephant!

Getting ready to go into Animal Kingdom. Super excited! We made good use of our

Memory Maker photo package. We're trying to get all the pictures that we

can, taken by the Photo Pass photographers. This is like a Magic Shot.

Yeah, it should have Pumbaa and Timon in it!

Announcer: Look closely. Keep an eye out. You never know what might appear, or who, as you begin a day of adventures in Disney's Animal Kingdom!

We're inside! There's the Tree of Life! That's an amazing sight, day or night.

Really cool at night because it lights up and animals are projected on it. They

move, and very cool!

Headed to Pandora!

Are you excited to be here, Cohen? Uh huh!

Going into Pandora.

Welcome to the valley of Mo' Ara, Pandora.

You see all sorts of strange plants!

The wait time for Flight of Passage is right now at 210 minutes. It's just a little after

nine o'clock and the park opened to the public at 9:00 am and to resort guests at

8:00 am for Early Magic Hours.

So many weird plants!

There's blue flowers up there! Do you see the blue flowers, Cohen?

And they all light up at night.

The Ma'vi River Journey is an 80-minute wait.

We're gonna get in that line right now.

There's the floating mountains!

Awesome!

Here's some of the bottoms of the Floating Mountains.

It has an interesting queue with all the different plant life, and vines, and the roof.

Its got information about Na'vi culture.

Now we're into the main queue.

The Shaman of Song is singing in the Na'vi language.

Find a drum!

Cohen's playing a drum.

That's cool!

One of the cool Mech suits from the movie.

And here's where you can buy, or adopt,

might be a better word, a Banshee.

They're animatronic.

They sit on your shoulder by a magnetic little clip that goes under

your shirt or coat. And pretty cool. They move around and make noises.

There's one.

It's like a puppet and you have a remote over there.

And it attaches to your shoulder if you want to wear it. Yeah, if you want to wear it on your shoulder. I just like to hold mine though. Yeah, that would be me...I'd just walk around with it. Very cool!

Does the Banshee choose you, or do you choose the Banshee?

So it'a a mutual bond, so you need to choose the Banshee, but the Banshee also needs to accept.

This is where you can have your own Avatar made of your face. You get scanned.

And you'll come out with one of these. It looks like you. There's someone over

there now getting his scan.

How much is it now to get one?

$74.99 plus tax.

How long does it take?

The scanning process is at least 5-7 minutes,

And you come back roughly in an hour to pick it up.

Thanator!!

Oh, he ate my camera!

There's some cool snacks here. That's a Rice Krispies Treat, or a Vein Pod.

This right here is called the Pandorean Tree Spores, but they're actually coconut

brownie bites!

Clear gummies.

Cilia. Those look like cilia.

Build your own Navi bracelet or necklace $19.99. And feathers! Let's make one!

Very cool gift shop. Very unique merchandise revolving around the world of Pandora.

We're at Pongu Pongu. Frozen beverages, draft beer, and a specialty snack spot.

Cool Na'vi hut.

You can get frozen beverages.

Some that light up. There's draft beer. water.

A Pongu Lumpia snack. It's a pineapple cream cheese roll.

And it's right next to Satu'li Canteen.

We're going into the Satu'li Canteen now. There's seating for guests that

are eating here only. This is the main restaurant in Pandora. Pongu Pongu is

more Grab 'n Go stuff, but this is a sit-down restaurant here.

And on the wall of the Satu'li Canteen, they have some official documents from the Alpha

Centauri expeditions.

It's called a Night Blossom.

Its got Boba balls in it; pear, limeade, apple.

How did you like yours, Daniel?

It wasn't great.

What is in that?? It's like super sour!

Well it's not for everybody. Might not be for anybody at this table!

What did you get, Donna?

It's called a Pandoran Sunrise.

Tastes like pineapple juice. Okay. But it tastes really good!

Has some Powerade mixed in with it.

And it's in a souvenir Flute Cup.

All I can taster is Powerade.

Strong on the Powerade, huh? Yes, very strong Powerade. I just love that it's juice mixed with Powerade!

That's a Blueberry Cream Cheese dessert.

That's actually very good. If you like cheesecake.

So, Blueberry Cream Cheese.

Get his reaction.

I have a very expressive face.

Is that egg on top?!?

Ha ha! No!

But it does kind of look like an egg.

This is white chocolate.

Try that.

Daniel's not so great on that one.

It's ok.

What's the yellow part...egg yolk?!?

Ha ha! It's not egg yolk!

It's lemon curd.

It's a little better with the lemon in it.

So, mix it together.

Oh, yeah. So put it together in one bite.

My turn to try it. What's the white thing on top of the lemon curd? Whipped cream?

Marshmallow cream?

It's kind of hard. Hard? Strange!

Okay, what did you think?

I liked it!

Cool! You like cheesecake though, a lot. You mix all the flavors together, I think it's better.

These are the coconut brownie bites.

Those eyes say it's good!

Too much coconut! Too much coconut for you!!!

For more infomation >> First Trip To Disney's Animal Kingdom Pandora World Of Avatar: Na'vi River Journey, Banshee, Dessert - Duration: 11:47.

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{Top Santé} Un remède naturel aux effets extraordinaires pour vos ongles - Duration: 1:57.

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Simplify Networking in a Hybr...

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How to Paint a watercolor landscape - Step by Step - Beginner painting tutorial│♥Alexandra ♥ - Duration: 10:21.

Hey guys, I hope you are all having an amazing day today and in this video I have a watercolor

painting tutorial of a forest.

I got a few requests in my forest watercolor painting video and I decided to film a tutorial

for anyone who is starting out with watercolours and wants to paint something simple.

The products I will be using are the following: My Winsor and Newton watercolor sketchers

pocket box.

One water brush, a calligraphy brush and a regular detail brush.

Some masking tape, The conda watercolor palette because I will be using one colour from this

paint set, cold pressed watercolour paper.

Some water and lastly paper towels.

In the description I have links to all the products I will be using in this video if

you guys are interested you can check them out.

To keep my watercolour paper sturdy and in one place while I am painting, I took some

masking tape and I taped it on to my wooden board.

Then I sprayed my watercolours with water to activate them and then I took some of the

colours I will be using to create a few mixtures to draw from.

Before I start painting I took a piece of paper to do some swatches of the colours I

will be using in order to decide which one to choose for my painting and also to do a

small demonstration for you guys as well.

For starters, I began mixing some colours to decide which one I wanted to use, I am

mixing some viridian hue with some ultramarine blue to come up with a deep turquoise colour

and then I added some phthalo blue as well.

Because our painting will consist of only one colour I want to create a quantity of

it so that we don't run out of it while we are painting.

When it comes to painting with watercolours it is almost impossible to to recreate the

exact same colour you created some other time.

Now I took some of the colour I just created and my detail brush and I drew a straight

vertical line as my tree trunk.

Then, I started drawing away from the trunk small straight lines that gradually get bigger

as we move downwards.

I began with the lighter colour and then I started layering it going back and forth in

horizontal motions.

I took some more paint and I went over the lines I just created to add another layer

of paint.

Then I drew a straight line again to re-define the trunk and I started mixing it while it

was still wet.

I started off by doing the wet on wet technique, I apply some water on my page using a fluffy

brush and then I added some blue into the mixture as my clouds.

I am tapping my brush into the watery page and I create small patches that look like

clouds.

While my paper is still wet, I try to distribute the paint I am using all over my page.

So, I started with adding some water into our paint to start with the lighter trees

in the background and then we will add more colour to paint the trees at the front, and

this will help us give our painting some more depth and dimension.

I try not to focus on the too much on details because the trees in the background will be

more fluffy and faint.

Then I started adding more colour into the puddle to increase the opacity of my paint

so that we can layer our pine trees.

While I am painting I am trying to spread the paint I already have on my brush for as

long as I possibly can while I move downwards.

Then I mixed some blue and green into our palette to create a darker colour.

Now I took my darker colour and I started painting the trees that are infront of the

very faint ones we just painted.

The way I am painting is drawing lines away from the tree trunk and they get thinner as

we paint and I am repeating the same process for all the trees.

To achieve those very thin lines I apply less pressure on my brush and when I want my brush

strokes to be thicker I apply more pressure on my brush.

And then again I am adding more blue and green into my puddle to increase the darkness and

opacity of my paint before I start painting the trees at the front.

And as you can see guys I am mixing some more turquoise colour to paint the trees again

at the front with a darker tone.

I don't know how many rows of trees we will be painting, in my previous time-lapse video

I think we painted 5 rows of pine trees but for this one maybe we will have 6 to give

it more dimension.

While I am painting these trees, I wanted to mention something that I mentioned earlier,

when I am move away from the tree trunk I put less pressure on my brush to achieve those

thinning lines towards the edges.

Now, I am moving to the 5th row of pine trees with a deep dark turquoise colour.

As my paint becomes darker and the opacity increases, the more I have to dip my brush

into the paint to continue painting, because it becomes more dry and the consistency of

it is much thicker.

I am painting horizontal lines one these trees to give my painting some deversity, i think

it makes the composition a little bit more interesting.

Then I picked up some black from the conda palette to mix into the colour that I am currently

using and I am also adding some water to increase the quantity as well.

Now my pine trees change in form a little bit, I drag this lines from the tree trunks

to the opposite direction horizontally and then I move downwards.

For the final row, I am adding more black into the paint mixture to achieve a very dark

colour.

For these trees I first drew the tree trunk and then I started dragging my brush from

the top using horizontal motions, It's sort of like drawing an endless line of Zs.

And finally, I gently remove the masking tape and there we have our watercolour landscape

painting.

So this is the finished painting, I hope you guys enjoyed this video and I will be posting

more soon.

If you would like to see more of my art I will have links available in the description

as well as my website shop with new limited edition prints.

Thank you guys so much for watching and I will see you in my next video.

Bye x