Saturday, September 30, 2017

Youtube daily report Sep 30 2017

Warning: Copper salts are toxic.

Sulfur dioxide is a toxic gas.

Sulfuric acid and hydrochloric acids are corrosive.

Wear gloves and work outside or in a fume hood.

Greetings fellow nerds.

In this video we're going to demonstrate yet another way to make sulfuric acid.

Our key ingredient this time is going to be copper chloride.

As usual i need to crush your expectations.

This is far more labor intensive and costly than just buying sulfuric acid directly.

In fact for the amount of work put into this you can probably get a better return

by getting a minimum wage job and then buying the acid with your earnings.

As usual our objective is to explore the science.

So let's get started wasting valuable hours of our life.

First we need a solution of copper (II) chloride.

I have about 150g in 400mL of water.

This was made in a previous video using copper metal and hydrochloric acid and used as a printed circuit board etchant.

Now the mixture for printed circuit board etchant tends to have a lot of excess hydrochloric acid.

It can still be used in this video but to help see the chemistry i distilled off the acid first and then added clean water back in.

I'll explain further why i did this as the video progresses.

Anyway, now we need a source of sulfur dioxide gas.

The most efficient way to make it is to burn sulfur and pump the sulfur dioxide gas into the reaction.

I'm going to instead use a sulfur dioxide generator that uses a solution of sodium metabisulfite and drips in hydrochloric acid.

This is overall a more expensive way of making sulfur dioxide but i'm using it because it's more convenient.

You can burn elemental sulfur instead.

Now we simply lead the gas into the solution of copper (II) chloride with vigorous stirring.

I placed the tube slightly above the surface of the solution to prevent backflow.

Anyway, Copper (II) chloride is an oxidant and reacts with the sulfur dioxide to form a mixture of sulfuric acid, hydrochloric acid, and copper (I) chloride.

The copper (I) chloride precipitates out as this white powder you see suspended in the solution.

Now the reason why i removed the excess hydrochloric acid from the copper chloride solution earlier

is because in concentrated solutions of hydrochloric acid the copper (I) chloride actually redissolves again

as it complexes with hydrochloric acid.

There is little visual indication of the reaction progressing.

While there is some color change the solution is too dark to notice.

At this point you might be wondering if other copper salts will work.

Copper bromide works but the resulting hydrobromic acid will reduce the sulfuric acid in the later steps.

Copper iodide doesn't form stable copper (II) salts so that can't be used.

Copper sulfate by itself doesn't react in this way so you have to have add halide ions for this to work.

Overall copper chloride is the best copper salt for this process.

Although you may substitute it with a mixture of copper sulfate

and a molar equivalent of hydrochloric acid since it'll form copper chloride in solution.

Anyway back to our reaction.

Now we can't add unlimited amounts of sulfur dioxide.

The copper (II) chloride can only absorb a half molar equivalent before it's depleted.

At this point we can separate our sulfuric acid

but we can instead regenerate our solution by changing our gas tube and this time bubbling in air.

The oxygen in the air slowly reoxidizes the copper (I) chloride into copper (II) chloride.

It helps to heat up the solution to between 60 and 90 celsius.

As the reaction progresses the copper (I) chloride will dissolve and the solution will become homogenous.

Unfortunately this oxidation step seems to be the achilles heel of this process.

It's incredibly slow.

I needed to bubble air for a full day before it all dissolved.

This makes the process very impractical for actual amateur synthesis of sulfuric acid

unless you start with kilograms of copper chloride and are very patient.

The main advantage of this process is that it's fully catalytic.

Once you regenerate the copper chloride solution you can bubble in additional sulfur dioxide to make more sulfuric acid.

Afterward you can repeat the cycle with more air.

Eventually though there will be so much sulfuric acid that it interferes with the absorption of gases and slows down the process.

I ran about 3 cycles before i decided i had enough.

For the last cycle don't regenerate the copper chloride.

Instead, let it precipitate and cool to room temperature.

Then filter the mixture to remove as much of the copper (I) chloride as possible.

This another reason why i removed the excess hydrochloric acid at the beginning.

If the copper (I) chloride remained dissolved it would make our sulfuric acid recovery much harder.

Now we have a solution of sulfuric acid, hydrochloric acid and small amounts of copper salts.

To separate our sulfuric acid distill off the remaining hydrochloric acid

and boil down with the maximum hotplate temperature until nothing distills over.

With the hydrochloric acid completely removed the sulfuric acid solution will precipitate out copper sulfate

and copper chloride salts that have very low solubility in high concentrations of sulfuric acid.

Now filter our sulfuric acid to remove the nearly insoluble copper chloride and copper sulfate salts.

And there we have it, sulfuric acid made by the copper chloride process.

It's slightly blue due to some to some minor copper contamination.

If you want you can distill the sulfuric acid using the high temperature heating mantle i showed an earlier video

to get pure concentrated sulfuric acid.

As for the copper salts and the bulk copper chloride from earlier,

now that we have removed the sulfuric acid we can regenerate it again.

Copper (I) chloride will oxidize on air somewhat so don't be surprised when it changes from white to a green, blue or even brown color.

Anyway, mix all the copper residues in a flask.

The copper sulfate in the distillation residue will feed forward to help make more sulfuric acid in the next run

so you don't need to worry about it building up.

Anyway, now once you've gathered all your copper chloride, add the hydrochloric acid that was distilled earlier.

You may need to top up extra water as the sulfuric acid carries away a small amount in its formation.

Now bubble air through the mixture to regenerate the copper (II) chloride.

Once it's dissolved, you are now ready to reuse the copper chloride to make more sulfuric acid.

Overall, the process does work and is catalytic.

The only consumed reactants are sulfur dioxide, water and air,

and the output is sulfuric acid, with everything else being recycled back in.

The catalyst, copper chloride, is very easy to make.

And as long as you're careful the process is much safer

and less toxic than some of my other processes like the electrobromine process.

In the end though i only got about 96 grams of sulfuric acid out of the three cycles i ran.

I'm not sure it's worth it for the labor involved.

The slowest part, the air oxidation, really hampers the utility of this process.

In theory you could bubble in air while simultaneously bubbling in sulfur dioxide for a continuous process.

But since the air oxidation is so slow you'll still be waiting long periods of time.

Now i know some of you would suggest using hydrogen peroxide.

I actually already showed in a previous video that hydrogen peroxide can oxidize sulfur dioxide and produce sulfuric acid directly.

No need for copper chloride catalyst in that case.

The drawback of hydrogen peroxide of course is that it's more expensive than air.

Nonetheless, there may be improvements to the copper chloride process with different concentrations of reactants,

hydrochloric acid and different temperatures.

I'll leave the optimizations up to anyone that wants to explore this process.

I have enough sulfuric acid as is.

So that is how you make sulfuric acid by the catalytic copper chloride process.

Thanks for watching.

Special thank you to all of my supporters on patreon for making these science videos possible

with their donations and their direction.

If you are not currently a patron, but like to support the continued production of science videos like this one,

then check out my patreon page here or in the video description.

I really appreciate any and all support.

For more infomation >> Make Sulfuric Acid by the Copper Chloride Process - Duration: 8:28.

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EPISODIO 1: ¡QUE NO SE TE QUEME EL ARROZ! - Duration: 7:44.

For more infomation >> EPISODIO 1: ¡QUE NO SE TE QUEME EL ARROZ! - Duration: 7:44.

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Punjabi Latest Unseen Pakistani Stage Mujra 2017 | NEW PAKISTANI MUJRA DANCE | DesiDanceTube - Duration: 2:48.

Punjabi Latest Unseen Pakistani Stage Mujra 2017 | NEW PAKISTANI MUJRA DANCE | DesiDanceTube

For more infomation >> Punjabi Latest Unseen Pakistani Stage Mujra 2017 | NEW PAKISTANI MUJRA DANCE | DesiDanceTube - Duration: 2:48.

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Father Figures Trailer

For more infomation >> Father Figures Trailer

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Ford S-Max Titanium 2.0-16V - Duration: 0:54.

For more infomation >> Ford S-Max Titanium 2.0-16V - Duration: 0:54.

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Make Sulfuric Acid by the Copper Chloride Process - Duration: 8:28.

Warning: Copper salts are toxic.

Sulfur dioxide is a toxic gas.

Sulfuric acid and hydrochloric acids are corrosive.

Wear gloves and work outside or in a fume hood.

Greetings fellow nerds.

In this video we're going to demonstrate yet another way to make sulfuric acid.

Our key ingredient this time is going to be copper chloride.

As usual i need to crush your expectations.

This is far more labor intensive and costly than just buying sulfuric acid directly.

In fact for the amount of work put into this you can probably get a better return

by getting a minimum wage job and then buying the acid with your earnings.

As usual our objective is to explore the science.

So let's get started wasting valuable hours of our life.

First we need a solution of copper (II) chloride.

I have about 150g in 400mL of water.

This was made in a previous video using copper metal and hydrochloric acid and used as a printed circuit board etchant.

Now the mixture for printed circuit board etchant tends to have a lot of excess hydrochloric acid.

It can still be used in this video but to help see the chemistry i distilled off the acid first and then added clean water back in.

I'll explain further why i did this as the video progresses.

Anyway, now we need a source of sulfur dioxide gas.

The most efficient way to make it is to burn sulfur and pump the sulfur dioxide gas into the reaction.

I'm going to instead use a sulfur dioxide generator that uses a solution of sodium metabisulfite and drips in hydrochloric acid.

This is overall a more expensive way of making sulfur dioxide but i'm using it because it's more convenient.

You can burn elemental sulfur instead.

Now we simply lead the gas into the solution of copper (II) chloride with vigorous stirring.

I placed the tube slightly above the surface of the solution to prevent backflow.

Anyway, Copper (II) chloride is an oxidant and reacts with the sulfur dioxide to form a mixture of sulfuric acid, hydrochloric acid, and copper (I) chloride.

The copper (I) chloride precipitates out as this white powder you see suspended in the solution.

Now the reason why i removed the excess hydrochloric acid from the copper chloride solution earlier

is because in concentrated solutions of hydrochloric acid the copper (I) chloride actually redissolves again

as it complexes with hydrochloric acid.

There is little visual indication of the reaction progressing.

While there is some color change the solution is too dark to notice.

At this point you might be wondering if other copper salts will work.

Copper bromide works but the resulting hydrobromic acid will reduce the sulfuric acid in the later steps.

Copper iodide doesn't form stable copper (II) salts so that can't be used.

Copper sulfate by itself doesn't react in this way so you have to have add halide ions for this to work.

Overall copper chloride is the best copper salt for this process.

Although you may substitute it with a mixture of copper sulfate

and a molar equivalent of hydrochloric acid since it'll form copper chloride in solution.

Anyway back to our reaction.

Now we can't add unlimited amounts of sulfur dioxide.

The copper (II) chloride can only absorb a half molar equivalent before it's depleted.

At this point we can separate our sulfuric acid

but we can instead regenerate our solution by changing our gas tube and this time bubbling in air.

The oxygen in the air slowly reoxidizes the copper (I) chloride into copper (II) chloride.

It helps to heat up the solution to between 60 and 90 celsius.

As the reaction progresses the copper (I) chloride will dissolve and the solution will become homogenous.

Unfortunately this oxidation step seems to be the achilles heel of this process.

It's incredibly slow.

I needed to bubble air for a full day before it all dissolved.

This makes the process very impractical for actual amateur synthesis of sulfuric acid

unless you start with kilograms of copper chloride and are very patient.

The main advantage of this process is that it's fully catalytic.

Once you regenerate the copper chloride solution you can bubble in additional sulfur dioxide to make more sulfuric acid.

Afterward you can repeat the cycle with more air.

Eventually though there will be so much sulfuric acid that it interferes with the absorption of gases and slows down the process.

I ran about 3 cycles before i decided i had enough.

For the last cycle don't regenerate the copper chloride.

Instead, let it precipitate and cool to room temperature.

Then filter the mixture to remove as much of the copper (I) chloride as possible.

This another reason why i removed the excess hydrochloric acid at the beginning.

If the copper (I) chloride remained dissolved it would make our sulfuric acid recovery much harder.

Now we have a solution of sulfuric acid, hydrochloric acid and small amounts of copper salts.

To separate our sulfuric acid distill off the remaining hydrochloric acid

and boil down with the maximum hotplate temperature until nothing distills over.

With the hydrochloric acid completely removed the sulfuric acid solution will precipitate out copper sulfate

and copper chloride salts that have very low solubility in high concentrations of sulfuric acid.

Now filter our sulfuric acid to remove the nearly insoluble copper chloride and copper sulfate salts.

And there we have it, sulfuric acid made by the copper chloride process.

It's slightly blue due to some to some minor copper contamination.

If you want you can distill the sulfuric acid using the high temperature heating mantle i showed an earlier video

to get pure concentrated sulfuric acid.

As for the copper salts and the bulk copper chloride from earlier,

now that we have removed the sulfuric acid we can regenerate it again.

Copper (I) chloride will oxidize on air somewhat so don't be surprised when it changes from white to a green, blue or even brown color.

Anyway, mix all the copper residues in a flask.

The copper sulfate in the distillation residue will feed forward to help make more sulfuric acid in the next run

so you don't need to worry about it building up.

Anyway, now once you've gathered all your copper chloride, add the hydrochloric acid that was distilled earlier.

You may need to top up extra water as the sulfuric acid carries away a small amount in its formation.

Now bubble air through the mixture to regenerate the copper (II) chloride.

Once it's dissolved, you are now ready to reuse the copper chloride to make more sulfuric acid.

Overall, the process does work and is catalytic.

The only consumed reactants are sulfur dioxide, water and air,

and the output is sulfuric acid, with everything else being recycled back in.

The catalyst, copper chloride, is very easy to make.

And as long as you're careful the process is much safer

and less toxic than some of my other processes like the electrobromine process.

In the end though i only got about 96 grams of sulfuric acid out of the three cycles i ran.

I'm not sure it's worth it for the labor involved.

The slowest part, the air oxidation, really hampers the utility of this process.

In theory you could bubble in air while simultaneously bubbling in sulfur dioxide for a continuous process.

But since the air oxidation is so slow you'll still be waiting long periods of time.

Now i know some of you would suggest using hydrogen peroxide.

I actually already showed in a previous video that hydrogen peroxide can oxidize sulfur dioxide and produce sulfuric acid directly.

No need for copper chloride catalyst in that case.

The drawback of hydrogen peroxide of course is that it's more expensive than air.

Nonetheless, there may be improvements to the copper chloride process with different concentrations of reactants,

hydrochloric acid and different temperatures.

I'll leave the optimizations up to anyone that wants to explore this process.

I have enough sulfuric acid as is.

So that is how you make sulfuric acid by the catalytic copper chloride process.

Thanks for watching.

Special thank you to all of my supporters on patreon for making these science videos possible

with their donations and their direction.

If you are not currently a patron, but like to support the continued production of science videos like this one,

then check out my patreon page here or in the video description.

I really appreciate any and all support.

For more infomation >> Make Sulfuric Acid by the Copper Chloride Process - Duration: 8:28.

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►我的箍牙記錄:箍牙半年了!牙醫說我的牙齒最近怎樣?|HY SHERRY - Duration: 3:34.

For more infomation >> ►我的箍牙記錄:箍牙半年了!牙醫說我的牙齒最近怎樣?|HY SHERRY - Duration: 3:34.

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How to: Your perfect Gigabyte Farming Simulator Gaming PC - builded from me 4 you - Duration: 7:52.

GIGABYTE Z370 AORUS GAMING 7 Mainboard

For more infomation >> How to: Your perfect Gigabyte Farming Simulator Gaming PC - builded from me 4 you - Duration: 7:52.

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Audi A4 Avant Lease Edition 2.0 TDI 90kW / 122pk S-tronic 21% Bijtelling! - Duration: 0:48.

For more infomation >> Audi A4 Avant Lease Edition 2.0 TDI 90kW / 122pk S-tronic 21% Bijtelling! - Duration: 0:48.

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Mini-Challenge: Malen mit dem #klassenfahrtdiary! - Duration: 1:15.

For more infomation >> Mini-Challenge: Malen mit dem #klassenfahrtdiary! - Duration: 1:15.

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Cette femme a découvert le meilleur moyen pour perdre du poids - France 365 - Duration: 6:07.

For more infomation >> Cette femme a découvert le meilleur moyen pour perdre du poids - France 365 - Duration: 6:07.

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[The 6th birthday of Star stable online] → Review of the game since 2011 ← - Duration: 4:15.

For more infomation >> [The 6th birthday of Star stable online] → Review of the game since 2011 ← - Duration: 4:15.

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성매매 영업 알고도 임대료 받은 건물주, 알선 혐의 유죄 - Duration: 3:51.

For more infomation >> 성매매 영업 알고도 임대료 받은 건물주, 알선 혐의 유죄 - Duration: 3:51.

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$50,000+ Bitcoin Could Happen if This Isn't a Bubble But an S-Curve - Duration: 10:12.

$50,000+ Bitcoin Could Happen if This Isn't a Bubble But an S-Curve

Countless experts and pundits, including Chase CEO Jamie Dimon, have proclaimed that Bitcoin is in a massive bubble right now, and it certainly could be.

Yet these "experts" fail to consider one possibility that some in the Bitcoin community are beginning to suspect: mass adoption may be imminent.

First, let's get something out of the way. Yes, with every bubble there are people who insist that it really isn't a bubble.

It's "the new normal" or "a new paradigm." Perhaps the most infamous such example is that of Yale economist Irving Fisher. At the height of the 1929 stock market bubble, just before the crash, a jubilant Fisher proclaimed:.

"Stock prices have reached what looks like a permanently high plateau. He couldn't have been more wrong. History is replete with examples of financial bubbles that popped disastrously.

Britain's South Sea bubble came about in the early 1700s, when investors became convinced that the South Sea Company, which was given a monopoly on trade with South America, would produce enormous profits.

Their hopes were dashed, and the entire economy shaken, when the bubble popped and the value of South Sea Company stock bottomed out.

The Mississippi bubble was caused when financier John Law convinced the French regent of a plan to pay off France's massive debts.

In 1716, Law's Mississippi Company agreed to assume the entire French national debt in return for a complete monopoly on all trade and mineral wealth in France's Louisiana territory.

Seeing no way to lose, and spurred to a frenzy by Law's marketing, investors drove the price of Mississippi Company stock sky high.

When Law realized the bubble had gotten out of hand, he tried to gradually deflate his stock price. Unfortunately, this resulted in a complete collapse of the company and wrecked the French economy.

Tulip mania is arguably the most famous bubble in history. In the 1630s, Dutch traders drove the price of tulip bulbs to absurd levels.

As prices kept rising, retail investors got involved in futures trading, betting on the price continuing to rise. At the bubble's peak, the price of a single tulip bulb was equal to the price of a riverfront home in Amsterdam.

Eventually the price stopped going up, people began to sell, and the price of tulip bulbs dropped to near zero.

The panic was so severe that the Dutch government offered to buy underwater futures contracts for 10% of the contracts' value, but continued price declines forced the government to withdraw its promise.

The two most famous bubbles of recent times are the dot-com bubble of the late-1990s/early-2000s and the housing bubble of the mid-2000s.

In the case of the dot-com bubble, people were so drawn to the potential of the Internet that they invested in any company with a ".com" in its name.

Venture capital and over-subscribed IPOs loaded these companies with so much cash that they didn't have to turn a profit right away.

Often with no business model at all, dot-com companies believed that if they attracted enough users, they would eventually find a way to profit. They were wrong, and the vast majority of them went bankrupt, tanking the value of the NASDAQ index.

The recent housing bubble was triggered by government policies and loose credit, enabling people to buy houses that were far beyond their financial means.

Seeing the demand, banks created derivatives which gave investors more ways to get exposure to the growing housing sector.

These derivatives added more fuel to the housing boom, as banks saw they could make outsized profits so long as the market continued to rise.

Lenders loosened credit restrictions even further, and anybody that said they wanted to buy a house was given a mortgage. Virtually no questions were asked and no documentation required.

Such mortgages were labelled "NINJA" loans: no job, no income, no assets were required to borrow money. Eventually buyers began defaulting on their mortgages en masse, causing a massive drop in housing prices and bringing about the Great Recession.

On S-Curves--why it really might be different this time. The adoption of new technologies over the last century has resembled an S-Curve. As the technology is introduced, it takes time for people to learn about it and realize its potential.

Once public awareness reaches a critical mass and the technology is perfected, adoption occurs extremely rapidly, resulting in exponential growth. Finally, once everybody has adopted the technology, the curve flattens out again. Key questions and bubble follow-up.

Below is a picture of the Bitcoin market since late 2013. See how even the "massive" bubble of November/December 2013 is dwarfed by the current one?.

What happens if today's Bitcoin bubble isn't a bubble at all, in the traditional sense? What happens if we are actually on the cusp of that massive near-vertical adoption uptake? A look back at the dot-com bubble and the housing bubble might shed some light on current circumstances.

On March 2, 2015, the NASDAQ index hit an all-time high, surging above the 5,000 mark as it finally surpassed its peak price, reached at the top of the dot-com bubble. Today, the index stands at 6,449.

It took 15 years, but the markets fully recovered, eventually reaching new highs. Likewise the Case-Shiller index of housing prices is approaching its pre-bubble heights. The index stopped at 198 in 2006 and is now back to 194.

As the economy continues to improve, it's likely that home prices will continue to rise above their 2006 peak.

Why did the South Sea bubble, Mississippi bubble, and Dutch tulip mania all eventually go to zero, never to rise again? Why did Internet companies enjoy a new resurgence and eclipse past bubble levels? Why do housing prices seem to be following the same path?.

More important, what does all this have to do with Bitcoin?. The bubbles of old were driven by hype, with nothing of value actually backing them. A tulip bulb has zero intrinsic value, and absolutely no potential to become something more.

The South Sea company was backed by a worthless monopoly, since South America was under Spanish control. The Mississippi company never could exploit the wealth of the new world, because unlike Spanish territories, Louisiana had no gold or silver to export.

Internet companies like Amazon, Facebook, PayPal and the others are completely different. The Internet offers unmatched potential for growth, with world-changing consequences.

Yes, things got overheated in the early 2000s, but prices recovered and the upward trajectory was renewed. Housing prices went out of control in the mid-2000s, but as the population grows, housing is always in demand.

A house represents a real asset with real value that meets a real need. Bitcoin represents a sea change in the way business is conducted on the Internet. It is the world's first decentralized, non state controlled, truly global currency.

Bitcoin is a promising monetary technology that seems more apt to follow the path of an S-Curve than that of a boom-and-bust.

Bitcoin could still be overpriced for this stage of its development. It could be in a bubble that deflates before rising again in a few years.

But if Bitcoin is what I think it is, then at some point (maybe even now) we will rapidly shoot up that S-Curve to prices that are presently unimaginable.

For more infomation >> $50,000+ Bitcoin Could Happen if This Isn't a Bubble But an S-Curve - Duration: 10:12.

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Voici comment perdre 5 kilos et 5 cm de tour de taille en seulement 4 jours - Duration: 5:35.

For more infomation >> Voici comment perdre 5 kilos et 5 cm de tour de taille en seulement 4 jours - Duration: 5:35.

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Vous pouvez perdre vos cheveux et entrer dans un état de coma en utilisant… - Duration: 6:37.

For more infomation >> Vous pouvez perdre vos cheveux et entrer dans un état de coma en utilisant… - Duration: 6:37.

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FINANCEMENT TERRORISME : LE SILENCE D'EN MARCHE ! - Duration: 8:18.

For more infomation >> FINANCEMENT TERRORISME : LE SILENCE D'EN MARCHE ! - Duration: 8:18.

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Voici comment perdre la graisse du ventre sans faire d'exercices ! - Duration: 6:17.

For more infomation >> Voici comment perdre la graisse du ventre sans faire d'exercices ! - Duration: 6:17.

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Chevrolet Kalos 1.4 16v Style (Airco/CPV/D-riem verv.) - Duration: 0:54.

For more infomation >> Chevrolet Kalos 1.4 16v Style (Airco/CPV/D-riem verv.) - Duration: 0:54.

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Isuzu D-max 2.5 4x4 LS 4000,- Voordeel - Dubbele Cabine - Grijs kenteken - Duration: 1:03.

For more infomation >> Isuzu D-max 2.5 4x4 LS 4000,- Voordeel - Dubbele Cabine - Grijs kenteken - Duration: 1:03.

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How the choice of a material allows it to reduce the environmental impact (the chair) - Duration: 2:01.

The challenge for the next 50 years will be maintain our very way of life improve

while reducing our impact on the environment.

We will see how the choice of materials can reduce our impact on

Environmental why we will take Example of a chair.

We chose three wood materials plastic and aluminum for each of it

will be interested in the extraction processing transport and recycling.

So using the example of a chair wood we'll start with extraction

so if we choose an exotic wood transport will obviously be very long,

pollution and the risk of very Deforestation great.

We can make the choice of certified wood that is to say following a sustainable management

forest and gasoline produced in the country of processing which reduces

trips therefore pollution.

In the case of the plastic chair, raw material, oil, and unsustainable

over the place of production is away transportation is very long which generates

pollution and requires a transformation in a petrochemical plant which is itself

pollution tress.

The alternative and sorting waste allowing through recycling to produce

plastic pellets of which may be used in the manufacture of our chair.

In the case of the aluminum chair the principle is the same as for the plastic chair

the raw material is also unsustainable and requires mining more

transport is long and processing requires a lot of energy all these factors

being highly polluting.

The alternative is the same as for plastic and is in the sorting of waste it allows

recover aluminum in all its forms of recycling the form of ingot

and reuse it to create our chair and without transportation except collection

garbage.

So we have seen that for each of three materials that can compose a chair

we have an alternative that reduces the environmental impact and that on the contrary

increases pollution, deforestation and uses non-sustainable resources.

To us in the future to make the right choice.

For more infomation >> How the choice of a material allows it to reduce the environmental impact (the chair) - Duration: 2:01.

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Amaury Vassili répond à vos questions ! Teaser n°2 - Duration: 1:54.

We would certainly at all costs want...

to do concerts, I and my musicians,

in other countries,

it's just a matter of where...

we try to go and what we're working on.

Singing in French closes doors too

so we will try to reopen them again,

why not by doing versions in different languages.

These are things that are being studied but there is nothing official and then ...

And...

I would say that....

...the country I might visit soon

would perhaps be Korea,

where I would like to do a concert again

and where I know things could get started.

But...

it's very difficult because we're in the process of creating an album,

kind of difficult to talk about

going abroad in the immediate future,

even though I would like it very much.

For me the most impressive country

remains Japan

because it was the greatest experience in my entire career

and then,

it has a special atmosphere.

Tokyo is an incredible city,

the people are really very welcoming.

In short, I felt good,

I also stayed a month, that's why it gave me a lot of memories and a lot of important things...

This made it an important destination

in my career and also in my life.

To be continued...

video and montage made by Amaury Vassili News&Projets Recorded at Wittenheim on the 23rd of September 2017

For more infomation >> Amaury Vassili répond à vos questions ! Teaser n°2 - Duration: 1:54.

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[The 6th birthday of Star stable online] → Review of the game since 2011 ← - Duration: 4:15.

For more infomation >> [The 6th birthday of Star stable online] → Review of the game since 2011 ← - Duration: 4:15.

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ACE - INTO THE WILD (prod.FANTE) - Duration: 2:58.

For more infomation >> ACE - INTO THE WILD (prod.FANTE) - Duration: 2:58.

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10 Creepy Photographs That Will Give You Chills - Duration: 10:07.

10 Creepy Photographs

Hey guys, Culture here. Today we're going to look through 10 of the creepiest photos

on the internet. Luckily Crash has already collated them into a folder on his desktop

in preparation for this video.

Aren't I the best?

Yes, Culture. The answer is yes.

Well credit where credit is due: You really were proactive on this one! You created this

folder almost 3 months ago! A hard-working lad if ever there was one.

You flatter me Culture, it was nothing really. But enough, let's give the people what they

came for!

Number 1: "Perfection Girl" is an image of a pretty

woman lying on a bed… Though there *is* something off about the way she's posed.

There are actually multiple images of the model on this bed, but the strangest part

about it is how it came to the internet's attention in the first place. The image was

posted on 4chan with a message telling users to see the "something hidden and shocking"

in the image.

Classic clickbait. Though we're the ones putting these pictures in a video so you know,

stones and glasshouses etc.

When confusion ensued, an anonymous poster said that the subject was, in fact, dead.

There's plenty of evidence to suggest that she's alive, at least at the time of the

photoshoot, but either way, this image has solidified itself in the mind of internet

denizens as a strange and creepy mystery. The question still lingers in my mind: "Could

it be true?"

And the question which still lingers in my mind is: "Isn't that Britney Spears?"

Number 2: "The Newby Monk" was taken in 1963 when

Reverend K. F. Lord decided to snap a picture of the altar of the Church of Christ the Consoler

in the UK.

K.F. Lord sounds more like a rapper than a Reverend. Maybe he's a Rapping Reverend?

Now *that* would be an act of God.

Supposedly, when he took this picture, there was no one else in the building, but the photo

itself shows a nine-foot tall figure dressed in robes and a white mask standing off to

the side. It's such a strange and mysterious-looking figure to appear in a place of worship that

it's quite chilling, even though many photography experts believe that the image itself was

doctored, possibly via double exposure.

So he's more of a Perjuring Priest than a Rapping Reverend.

Number 3: "This guy showed up in one of my pictures,"

is an image uploaded to imgur by Reddit user, ZombieGadaffi. It's of their uncle during

a vacation to the Grand Canyon. The story goes that the uncle wished to take a funny

picture at the edge. After he and his friends got the images developed, they discovered

a strange hooded figure standing in the background. No one in ZombieGaddaffi's family knows

who it is, and the user believes that their family is telling the truth.

And of course we should all trust a guy with the name ZombieGadaffi.

Whoever this figure is, he, or it, was there at the canyon when there was no one else around,

making him either a ghost, or a master at stealth!

Or a pale kid in a hoodie. Yep, I'm definitely gonna go with pale kid in a hoodie

Number 4:

"The World's Most Beautiful Suicide" is a picture of the corpse of Evelyn McHale.

It was taken by Robert Wiles, and, as the name suggests, shows the body in a state of

serene rest, surrounded by the destruction of the limo that she landed on. The event

occurred in 1947 on the 30th of April, when McHale travelled to the Empire State Building.

From the 86th floor, she jumped, landing on the car in the position in which she was found.

The 86th floor?! Maybe she just couldn't bear the thought of climbing back down all

those stairs,

On her person was a suicide note, which read: "I don't want anyone in or out of my family

to see any part of me…" Unfortunately for her, the manner of her death has not only

allowed her family to see her, but the whole world to marvel at the sight.

That poor, poor... limo driver.

Number 5: "I am God/We All Die" - This horrifying

screaming face is the result of a series of threads on 4chan's /x/ board. It all started

when a user asked the /x/ community if it was possible if computers could be haunted.

The reason the user asked this is because mysterious files would appear on the computer.

When /x/ asked if they could see the files, two pictures were uploaded to the site. What

followed was an, ARG style, scavenger hunt for more pieces of the picture, coupled with

users experiencing paranormal experiences involving the face from the image. Eventually,

a user was able to send the completed file over to a phone number that had called the

anon earlier, only to receive pictures of knives and dolls in response.

I mean it's still better than receiving ACTUAL knives and dolls in response. That

Chucky still freaks me out

Number 6: "The Russian Sleep Experiment" is a formative

creepypasta. Like many creepypasta out there, an iconic image is usually associated with

it, spread around the internet and distorted until its origins are unknown. While we can't

say for certain where the image itself comes from, we can point out the terrifying subject

of the image. It is actually a latex Halloween prop known as "Spazm," which features

a psychotic man in a straight jacket.

What a waste of good latex. Latex is supposed to be sexy people, not scary! And then there's

Scary Spice who wears latex and is both scary *and* sexy… no wonder my fetishes are so

messed up.

When activated, "Spazm" will shake and growl, laughing maniacally. An updated version

of this prop is still sold online, but it looks slightly different than the original

version, available since the mid-2000s.

Number 7: Reynaldo Dagsa Assassination- Manilan councillor

Reynaldo Dagsa was taking an opportunity to photograph his family outside of his home,

but to the left of the subjects, you can clearly see Arnel Buenaflor, pointing a gun at the

camera. This photo was taken by Councilor Dagsa a moment before he was fatally shot

by Buenaflor, and the image was later used for evidence, leading to his arrest. One has

to wonder if this crime would have ever been punished, had this politican not decided to

have one last family photo before his demise. The killer and his accomplices are members

of the Pasaway Gang, and it is believed that they targeted Dagsa because of his peacekeeping

efforts.

Buenaflor was actually just trying to save Dagsa's family…

What?

Because Dagsa said he was going to ~shoot~ his family… get it? hahaha god I'm funny.

Number 8:

Six Flags is franchise of amusement parks throughout the United States of America, offering

sun rides based on Warner Bros. Properties, among other things, but today, you won't

find anyone at the New Orleans location, save for urban explorers and the police who guard

it daily, and it has been that way since August of 2005. When Hurricane Katrina devastated

the city, Six Flags decided that it did not want to repair the park, and terminated its

contract with the city. Since then, the Industrial Development Board of New Orleans keeps it

under close security prevent visitors from trespassing.

This place looks like somewhere those guys on American Pickers would go. Not really that

scary.

I guess the fear comes from the memory of the disaster that left what was once a place

of happiness in ruin. The scariest things can be those that are out of our hands, a

haunting reminder of our own frailty in the face of nature…

Jeez okay, I get it.

Number 9:

In Pennsylvania, there was once the legend of a being known as "the Green Man." This

mysterious entity would roam the streets at night, glowing green in the headlights of

the cars that passed him by. Many tales came up about the Green Man, a horrific monster

of a man turned green from an electrical shock.

See, people get away with calling him the Green Man but can you imagine the outrage

if he called an Asian guy the Yellow Man? These are the double standards we should be

addressing.

Crash… shut up. In reality, Raymond Robinson was electrocuted but it didn't leave his

skin green… it just destroyed his face. Because of his horrific appearance, he stayed

inside most of the time, and he would go on walks in the night time. This is when drivers

would come by just to gawk at him. Though we don't know where this picture comes from,

apparently he would sometimes allow his photo to be taken by curious individuals in exchange

for beer or cigarettes.

I also engage with curious individuals for beers or cigarettes but I have to do more

than just let them take photos of me.

Eww.

Number 10: The SCP foundation has a wide collection of

articles on creepy and paranormal things made up based on images found online. But, even

the users of the main SCP site were having trouble finding the origin of the image associated

with an early entry, SCP-1067 "The Old Man." A thread on the SCP foundation website brought

up that all reverse image searches brought back results relating to SCP-106. Later, it

was discovered that Dr. Gears, the writer of the piece had found the image on a 4chan

/x/ thread, making its origin unknown. An attempt from Reddit links the image to that

of Len Kleinrock taken for the 40th anniversary of the first internet transmission. The two

share a similar smile, yet this is only a possibility for where SCP-106's face comes

from.

EWW they share a similar smile?! That's the worst part of the picture!

It's okay Crash, it's over now. Honestly I'm surprised you managed to look them all

up without getting scared or something. But I'm glad you did, and I'm glad you took

the initiative to get the research done without me having to nag you! Though now I think about

it… I only gave you this assignment 2 weeks ago. So why was this folder created 3 months

ago..?

Like I said, I do way worse things for some beers and cigarettes.

You are the creepiest person I know Crash.

Nawwwww thanks Culture

For more infomation >> 10 Creepy Photographs That Will Give You Chills - Duration: 10:07.

-------------------------------------------

Kennedy Classics - Grace and Law - Duration: 28:31.

FROM D. JAMES KENNEDY MINISTRIES

THIS IS KENNEDY CLASSICS

WELCOME TO KENNEDY CLASSICS

HELLO, I'M FRANK WRIGHT, PRESIDENT OF

D. JAMES KENNEDY MINISTRIES WHERE WE ARE STANDING FOR

TRUTH AND DEFENDING YOUR FREEDOM.

WELCOME TO KENNEDY CLASSICS.

BE SURE TO VISIT OUR MINISTRY WEBSITE,

DJKM.ORG, WHERE YOU CAN FIND AN ABUNDANCE OF

DIGITAL, AUDIO, VIDEO, AND PRINT RESOURCES.

IT HAS BEEN SAID THAT "IF YOU CAN'T EXPLAIN IT TO A

SIX YEAR OLD, YOU DON'T UNDERSTAND IT YOURSELF."

SIMPLY PUT, IF YOU DON'T KNOW HOW TO BOIL SOMETHING

DOWN TO ITS BARE ESSENTIALS, THEN YOU DON'T

FULLY GRASP THAT THING.

THAT QUOTE HAS OFTEN TIMES BEEN ATTRIBUTED TO ALBERT

EINSTEIN, PROBABLY REFERENCING AN ASPECT OF

QUANTUM MECHANICS, BUT THE POINT BEING MADE IS STILL

PERTINENT TO US.

THINK ABOUT YOUR UNDERSTANDING OF THE BIBLE

AND OF THEOLOGY.

GOD'S WORD IS CHOCK-FULL OF COMPLEXITIES AND

INTRICACIES THAT SOME THEOLOGIANS WILL SPEND

DECADES STUDYING, AND SOMETIMES NEVER FULLY

UNDERSTANDING.

DR. KENNEDY POSITS THAT IN ORDER TO UNDERSTAND THE

ESSENTIALS OF THE BIBLE, YOU MUST LOOK AT TWO

THINGS, GRACE AND LAW.

THESE TWO THINGS HAVE BEEN MISCONSTRUED BY MANY, AND

UNDERSTANDING THE RELATIONSHIP THEY SHARE

IS VITAL TO FULLY UNDERSTANDING GOD'S WORD.

HERE THEN IS DR. D. JAMES KENNEDY WITH HIS MESSAGE:

"GRACE & LAW."

OUR SCRIPTURE LESSON THIS MORNING IS TAKEN FROM THE

THIRD CHAPTER OF PAUL'S LETTER TO THE ROMANS,

ROMANS CHAPTER 3, AND WE SHALL BEGIN OUR READING

WITH THE 19TH VERSE.

I HOPE YOU HAVE YOUR BIBLE WITH YOU TO FOLLOW ALONG

WITH ME.

IT IS NO DOUBT OF SMALL IMPORTANCE IN THE COSMIC

SCHEME OF THINGS BUT GREAT IMPORTANCE TO ME, PERHAPS

A MATTER OF LITTLE CURIOSITY TO YOU THAT I

MIGHT MENTION THAT VERSES 19 AND 20 WERE THE VERSES

THAT GOD USED TO BRING ME OUT OF DARKNESS INTO LIGHT

AND THROUGH WHICH I WAS CONVERTED TO CHRIST.

MAY THEY HAVE A SIMILAR IMPACT ON SOME LIVES HERE

TODAY.

MAY WE HEAR THE INSPIRED WORD OF THE LIVING GOD.

AND MAY GOD SPEAK TO OUR HEARTS AND MINDS THIS DAY

THROUGH THIS HIS HOLY WORD AND MAY HIS NAME EVER BE

PRAISED AMEN.

WELL, WE LIVE IN AN AGE OF INCREDIBLE BIBLICAL

ILLITERACY.

THE AVERAGE AMERICAN TODAY HARDLY HAS A CLUE AS TO

WHAT IS FOUND BETWEEN THE COVERS OF THIS VOLUME.

PERHAPS EVEN MORE TRAGICALLY, THE MAJORITY

OF THE PEOPLE IN THE CHURCH DON'T KNOW MUCH

MORE ABOUT IT.

WHAT DOES IT CONTAIN?

WHAT IS THE GREAT MESSAGE OF IT?

WELL ESSENTIALLY, IF YOU ARE TO UNDERSTAND IT, YOU

MUST UNDERSTAND THAT IT CONTAINS TWO THINGS: ONE

IS LAW AND THE OTHER IS GRACE.

THOSE ARE GREAT CONCEPTS, TREMENDOUS PRINCIPLES, AND

VERY FEW AMERICANS KNOW WHAT BOTH OF THEM REALLY

MEAN AND FEW CHURCH MEMBERS REALLY KNOW HOW

THEY FULLY RELATE ONE TO ANOTHER.

THE LAW, OF COURSE, TELLS US WHAT WE ARE SUPPOSED TO DO.

THESE ARE THE COMMANDMENTS OF GOD: "THUS SHALT THOU

DO", THE SCRIPTURE SAYS MANY AND MANY A TIME.

THE FIRST MISUNDERSTANDING THAT WE SEE AS WE LOOK AT

THE LEVELS OF THE LACK OF UNDERSTANDING OF THE

SCRIPTURE IS THE FACT THAT THERE ARE MILLIONS OF

AMERICANS, AND I WOULD SAY APPROXIMATELY 60% OF THE

AMERICAN PEOPLE BELIEVE THAT WE SHALL GAIN

ENTRANCE INTO PARADISE BY THE METHOD OF THE LAW-

THAT THE LAW PRESENTS A LADDER THAT WE ARE TO

CLIMB UP INTO HEAVEN.

NOW THAT ERROR IS SO WIDESPREAD THAT IT CAUSED

DR. WILLIAM CHILDS ROBINSON, THE GREATEST

SCHOLAR I EVER STUDIED UNDER, TO SAY SOMETHING

WHICH I HAVE SAID BEFORE, BUT WOULD LIKE TO INSCRIBE

IT ON THE WALLS OF YOUR MEMORY.

AS YOU CAN'T DO THAT, AT LEAST HANG IT UP ON YOUR

REFRIGERATOR.

IF YOU UNDERSTAND THIS, YOU WILL UNDERSTAND WHAT

THE BIBLE IS ALL ABOUT, BUT I GUARANTEE YOU THAT

THERE IS PROBABLY A MINORITY OF PEOPLE IN THIS

SANCTUARY RIGHT NOW THAT FULLY UNDERSTAND IT.

HE SAID: "CHRIST ALWAYS HAS BEEN AND ALWAYS WILL

BE CRUCIFIED BETWEEN TWO THIEVES- LEGALISM AND

LICENSE," AND THERE IS A TREMENDOUS AMOUNT OF TRUTH

IN THAT STATEMENT.

LET ME SAY IT AGAIN, CHRIST ALWAYS HAS BEEN AND

ALWAYS WILL BE CRUCIFIED BETWEEN TWO THIEVES-

LEGALISM AND LICENSE.

WELL THE LEGALISTS ARE THOSE WHO SUPPOSE THAT BY

FOLLOWING SOME LEGAL CODE, BY LIVING BY THE

COMMANDMENTS OF GOD, THEY WILL GAIN ACCEPTANCE INTO

HEAVEN.

NOW I AM FULLY AWARE AND QUITE FAMILIAR WITH THAT

SCHOOL OF THOUGHT BECAUSE I ONCE WAS A PART OF IT

MYSELF.

FOR THE FIRST 24 YEARS OF MY LIFE, I WAS FULLY UNDER

THE IMPRESSION THAT ONE GOT TO HEAVEN BY BEING

GOOD, BY FOLLOWING THE LAW.

YOU CAN THEREFORE WELL IMAGINE THE IMPACT THAT

THOSE TWO VERSES THAT I READ THIS MORNING HAD UPON

ME.

NOW WE KNOW THAT "WHAT THINGS SO EVER THE LAW

SAITH, IT SAYS TO THEM WHO ARE UNDER THE LAW THAT

THEY MAY MAKE THEIR WAY TO HEAVEN".

THAT'S NOT WHAT IT SAYS, IS IT?

IT SAYS TO THOSE WHO ARE UNDER THE LAW: "THAT EVERY

MOUTH MAY BE STOPPED, AND THE WHOLE WORLD MAY BECOME

GUILTY BEFORE GOD (ROMANS 3:19)."

THE LAW WAS NOT GIVEN TO MAKE YOU INNOCENT; THE LAW

WAS GIVEN TO SHOW YOU HOW GUILTY YOU ARE.

HE GOES ON TO SAY, "THEREFORE BY THE DEEDS OF

THE LAW THERE SHALL NO FLESH BE JUSTIFIED IN HIS

SIGHT: FOR BY THE LAW IS THE KNOWLEDGE OF SIN"

AND SO THE LAW CONDEMNS US.

IT DOESN'T SAVE US.

THE LAW SHOWS US OUR VILENESS.

AS MARTIN LUTHER SAID, THE LAW IS A MIRROR THAT SHOWS

US OUR UNCLEANNESS, IT IS A HAMMER THAT SMASHES OUR

SELF-RIGHTEOUSNESS AND HUMBLES US IN THE DUST,

AND IT IS A WHIP THAT DRIVES US TO THE CROSS

FOR MERCY.

NOW THERE ARE SOME RIGHT HERE IN THIS ROOM, I HAVE

NO DOUBT, WHO ARE UNDER THE DELUSION THAT BY

TRYING TO LIVE A GOOD LIFE, BY GOING TO CHURCH,

BY HELPING YOUR NEIGHBOR, BY DOING THE BEST YOU CAN,

THAT YOU ARE PROBABLY GOING TO GET TO HEAVEN

SOMEDAY.

YOU ARE NOT.

LET IT BE SAID AS CLEARLY AND PLAINLY AS IT CAN BE

SAID: SHOULD YOU CONTINUE ON THAT ROAD, YOU WILL

DISCOVER THAT THE BRIDGE IS OUT AND YOU WILL LAND

IN HELL.

"NO FLESH SHALL BE JUSTIFIED BY THE LAW,

FOR BY THE LAW IS THE KNOWLEDGE OF SIN."

NOW OVER AGAINST THAT WE HAVE ANOTHER PRINCIPLE-

A PRINCIPLE WHICH IS ANTITHETICAL TO THE LAW,

A PRINCIPLE WHICH IS UNKNOWN, REALLY,

TO THIS WORLD.

IT IS A PRINCIPLE THAT IS DIVINE.

IT IS THE PRINCIPLE OF GRACE.

GRACE IS THE TOTALLY UNMERITED, AND UNDESERVED

AND UNEARNED FAVOR OF GOD.

IT IS THE MERCY OF GOD GIVEN TO THOSE WHO

POSITIVELY DO NOT DESERVE IT.

IT IS GOD ACCEPTING US NOT BECAUSE OF ANYTHING THAT

WE HAVE DONE, BUT IN SPITE OF EVERYTHING THAT WE HAVE

DONE.

EVERYBODY IN HEAVEN KNOWS ONE THING VERY CLEARLY:

HE OUGHT TO BE IN HELL.

AND IF YOU DON'T KNOW THAT, YOU WILL NEVER SEE

THE INSIDE OF HEAVEN.

HEAVEN IS FOR PEOPLE THAT OUGHT TO GO TO HELL.

YOU SEE, THERE AREN'T ANY OTHER KIND OF PEOPLE

ON THIS PLANET.

"YE ARE CONDEMNED ALREADY", SAID CHRIST.

JESUS CHRIST CAME DOWN FROM HEAVEN BECAUSE WE

WERE ALL ON OUR WAY DOWN TO HELL.

AND HE CAME TO DELIVER THOSE THAT WERE PERISHING.

GRACE IS THE FREE MERCY AND ACCEPTANCE OF GOD

BASED UPON THE FINISHED ATONING WORK OF JESUS

CHRIST.

THE CONTRAST BETWEEN THE TWO IS ENORMOUS.

THE LAW SAYS "DO" AND GRACE SAYS "DONE"

THE LAW SAYS, "PAY ME THAT WHICH THOU OWEST".

GRACE SAYS, "I FREELY FORGIVE THEE OF ALL OF

THY DEBTS".

THE LAW SAYS, "THE WAGES OF SIN IS DEATH".

AND GRACE SAYS, "THE GIFT OF GOD IS ETERNAL LIFE

THROUGH JESUS CHRIST OUR LORD".

THE LAW SAYS, "THE SOUL THAT SINNETH, IT SHALL

SURELY DIE".

AND GRACE SAYS, "WHOSOEVER BELIEVETH ON JESUS SHALL

NEVER DIE".

SO SALVATION IS ENTIRELY AND TOTALLY AND COMPLETELY

BY GRACE THROUGH FAITH IN JESUS CHRIST, FROM

BEGINNING TO END, FROM START TO FINISH, FROM

ETERNITY TO ETERNITY.

BUT THEN, ON THE OTHER SIDE OF THE LEGALIST THERE

ARE THOSE WHO BELIEVE IN LICENSE.

THE THIEF OF LICENSE.

WHAT IS LICENSE?

LICENSE IS THE ATTITUDE OF HEART THAT THROWS OFF ALL

RESTRAINTS OF LAW- THE ATTITUDE THAT CHRIST

TALKED ABOUT WHEN HE PUT INTO THE MOUTHS OF SOME IN

ONE OF HIS PARABLES THE WORD, "WE WILL NOT HAVE

THIS MAN TO REIGN OVER US".

THOSE WHO SAY THEY WILL NOT BE UNDER THE AUTHORITY

OF ANY OTHER.

HOW FOOLISH THEY ARE, FOR THE BIBLE MAKES IT VERY

CLEAR THAT THERE ARE ONLY TWO KINDS OF PEOPLE,

REALLY, IN THIS WORLD.

THERE ARE THOSE WHO ARE UNDER THE BONDAGE AND

TYRANNY OF SIN, AND THERE ARE THOSE WHO ARE UNDER

THE BONDAGE TO RIGHTEOUSNESS, WHICH

MEANS, TO PERSONIFY THAT, WE ARE EITHER IN BONDAGE

TO SATAN OR WE ARE IN BONDAGE TO CHRIST.

THERE IS NO MIDDLE GROUND.

THOSE WHO SUPPOSE THEMSELVES TO BE

AUTONOMOUS ARE THE MOST USEFUL SLAVES OF THE

DEVIL.

THOSE WHO SUPPOSE THEMSELVES TO BE

COMPLETELY FREE ARE QUITE USEABLE BY SATAN.

THOSE WHO REJOICE IN THEIR FREE WILL, WHAT DID MARTIN

LUTHER SAY?

HE SAID THE FREE WILL OF FALLEN MEN IS LIKE A DUMB

BEAST RIDDEN BY THE DEVIL WHO TURNS IT WITHER SO

EVER HE WILL.

MY FRIENDS, THERE IS NOTHING ELSE.

WE ARE EITHER UNDER THE DOMINION OF SATAN OR WE

ARE UNDER THE DOMINION OF CHRIST WHO SETS US FREE

FROM BONDAGE TO SATAN, THIS IS WHAT THE ENTIRE

SIXTH CHAPTER OF ROMANS IS ALL ABOUT.

HAVING BEEN SET FREE FROM THE BONDAGE OF SIN WE

BECOME THE SERVANTS OF RIGHTEOUSNESS.

AS LUTHER ALSO SAID, "HE IS MOST FREE WHO IS THE

BOND SLAVE OF JESUS CHRIST".

NOW, I HAVE TALKED TO MANY OF THOSE, BY THE WAY, THE

THEOLOGICAL TERM FOR THOSE WHO FEEL THAT THE LAW HAS

NOTHING TO DO WITH CHRISTIANS.

BY THE WAY, THE FIRST HERESY TRIAL EVER CARRIED

ON IN AMERICA OVER 300 YEARS AGO WAS AGAINST A

MAN WHO WAS CHARGED WITH THIS HERESY.

IT'S CALLED ANTINOMIANISM.

NOMAS IS THE GREEK WORK FOR LAW.

ANTINOMAS IS TO BE AGAINST THE LAW.

A PERSON WHO IS ANTINOMIAN IS A PERSON WHO FEELS THAT

THE LAW HAS BEEN DONE AWAY WITH AND "I HAVE NOTHING

TO DO WITH IT ANY LONGER".

WELL I HAVE TALKED TO NUMBERS OF THOSE PEOPLE

AND I HAVE TALKED TO GROUPS, AND I'VE SAID TO

THEM THIS: IF THE LAW IS GONE AWAY COMPLETELY, THEN

I WANT YOU TO NAME ONE THING THAT YOU AS A

CHRISTIAN COULD DO THAT WOULD PLEASE GOD THAT IS

NOT OBEYING HIS LAW.

I HAVE ASKED FOR 25 OR 30 YEARS I'VE ASKED PEOPLE

THAT QUESTION.

I'VE NEVER HAD ANYBODY COME UP WITH AN ANSWER.

OH YES THERE WAS ONE PERSON WHO SUBMITTED AN

ANSWER AND SHE THOUGHT THIS WAS A BRILLIANT

RESPONSE.

SHE SAID, "WELL, WE COULD LOVE GOD".

LOVE GOD?

HAVE WE FORGOT JESUS SAID THE FIRST AND GREATEST

COMMANDMENT IS THIS: "THOU SHALT LOVE THE LORD THY

GOD WITH ALL OF THE HEART, MIND, STRENGTH AND SOUL".

NOT ONLY IS THAT A COMMANDMENT, IT IS THE

FIRST AND GREATEST OF ALL THE COMMANDMENTS.

OF COURSE, WE SHOULD LOVE GOD, BUT THAT IS A

COMMANDMENT.

AND I WOULD ASK YOU: CAN YOU THINK OF ANYTHING THAT

YOU MIGHT DO THAT WOULD PLEASE YOUR HEAVENLY

FATHER OTHER THAN OBEYING HIS LAWS?

LET ME TELL YOU THIS.

GOD IS DISPLEASED WITH PEOPLE WHO TRY TO INVENT

THINGS, AND THERE HAVE BEEN THOSE IN THE CHURCH

WHO HAVE TRIED TO INVENT THINGS TO DO, IN HUMAN

INVENTION AND WISDOM, WHICH THEY THINK MIGHT

PLEASE GOD.

GOD SAYS IN HIS WORD, "WHO HATH COMMANDED THEE TO

THUS TRAMPLE MY COURTS?

I DID NOT COMMAND YOU TO DO THAT.

WHY ARE YOU DOING IT?"

THERE IS NOT ONE SINGLE THING THAT YOU COULD THINK

OR FEEL OR SAY OR DO THAT WOULD PLEASE GOD OTHER

THAN KEEPING HIS COMMANDMENTS.

WHAT DID JESUS SAY?

"IF YOU LOVE ME, FORGET MY COMMANDMENTS?"

THAT'S NOT WHAT HE SAID.

I WOULD HOPE EVERYBODY HERE KNOWS THAT, BUT THESE

DAYS, YOU CAN'T BE SURE.

HE SAID, OF COURSE, "IF YE LOVE ME, KEEP MY

COMMANDMENTS".

WHAT DO WE FIND HERE IN THIS PASSAGE OF PAUL WHERE

HE JUST HAS CONCLUDED THAT WE ARE SAVED BY FAITH

ALONE WITHOUT THE DEEDS OF THE LAW?

WELL, LOOK TO THE 31ST VERSE.

JUST GO AHEAD THREE MORE VERSES AND YOU SEE THIS.

"DO WE THEN MAKE VOID THE LAW THROUGH FAITH?"

AND WHAT DOES THE ANTINOMIAN SAY?

"YEA, AND AMEN, WE MAKE VOID THE LAW.

WE GET AWAY FROM THE LAW.

WE'VE DONE IT IN.

WE DON'T HAVE THE LAW ANYMORE.

WE CAN DO ANYTHING OUR LITTLE SINFUL HEART

PLEASES.

WE'VE BEEN SET FREE TO BE LAWLESS".

IT'S INTERESTING THAT THE BIBLE DESCRIBES THAT FINAL

AGE BEFORE CHRIST COMES BACK AS AN AGE OF

LAWLESSNESS.

BUT THAT'S NOT WHAT PAUL SAID.

READ IT, MY FRIENDS.

"DO WE THEN MAKE VOID THE LAW THROUGH FAITH?"

GOD FORBID.

ME GENOITO, WHICH IN GREEK IS A VERY STRONG

STATEMENT- "LET IT NOT BE SPOKEN, THINK IT NOT,

SAY IT NOT."

YEA, WE ESTABLISH THE LAW.

AS IN THE OLD TESTAMENT PROPHECY OF THIS AGE, WHEN

WE WOULD BE SPRINKLED WITH CLEAN WATER AND BE MADE

CLEAN, AND GOD SAYS, "I WILL WRITE MY COMMANDMENTS

ON THE FLESHLY TABLETS OF THEIR HEART", NOT JUST

UPON TABLETS OF STONE, BUT UPON OUR HEARTS, THAT AS

LOVING SONS AND DAUGHTERS, WE WILL DELIGHT TO PLEASE

OUR HEAVENLY FATHER BY FOLLOWING HIS

COMMANDMENTS.

HAS THE LAW BEEN ANNULLED?

GOD FORBID.

LOOK ALL THE WAY TO THE VERY LAST CHAPTER OF THE

BIBLE, MY FRIENDS, YOU SEE IT STILL THERE.

IF YOU LOOK IN 12:17 YOU READ ABOUT THE SEED WHICH

KEEP THE COMMANDMENTS OF GOD AND HAVE THE TESTIMONY

OF JESUS CHRIST.

OR IN THE 14TH CHAPTER, "HERE IS THE PATIENCE OF

THE SAINTS: HERE ARE THEY THAT KEEP THE COMMANDMENTS

OF GOD, AND THE FAITH OF JESUS.

OR TO THE VERY LAST CHAPTER OF THE BIBLE,

CHAPTER 22 OF REVELATION, VERSE 14, "BLESSED ARE

THEY THAT DO HIS COMMANDMENTS".

ARE YOU AN ANTINOMIAN?

DO YOU DESPISE HIS LAW?

"O HOW I LOVE THY LAW", SAID DAVID.

"I MEDITATE UPON IT DAY AND NIGHT."

MAY GOD, BY HIS INCREDIBLE GRACE, WHO HAS SAVED US

AND WHO KEEPS US BY THAT GRACE, UNMERITEDLY, AND WE

KNOW THAT WE WILL NEVER BE ABLE TO KEEP THAT LAW IN

ANY WAY THAT COULD POSSIBLY MAKE US

ACCEPTABLE TO GOD.

BUT OUT OF THE LOVE THAT HE WORKS IN OUR HEARTS, WE

WILL STRIVE TO PLEASE HIM.

MAY GOD DO THAT WORK IN EVERY ONE OF OUR HEARTS.

LET US PRAY.

FATHER, THERE ARE SOME HERE TODAY WHO STILL ARE

WANDERING AROUND IN THE DESERT OF LEGALISM, WHO

ARE STRIVING TO CLIMB THE MOUNTAIN OF LAW TO MAKE

THEMSELVES ACCEPTABLE TO THEE.

MAY THEY HEAR THY WORD AGAIN THAT THERE IS NONE

THAT KEEPETH IT, THAT WE ARE TOGETHER BECOME

UNPROFITABLE.

MAY THEY CAST THEMSELVES AT THE FOOT OF THE CROSS

AND SAY, "O LORD JESUS CHRIST THAT FOR WHICH

YOU ARE DYING IS MY VIOLATIONS OF THE LAW.

DAY AFTER DAY, HOUR AFTER HOUR IN THOUGHT, IN WORD,

IN DEED, IN OMISSION AND COMMISSION, I HAVE

VIOLATED ALL OF YOUR COMMANDMENTS AND NOW STAND

GUILTY BEFORE THEE WITH MY HAND OVER MY MOUTH AND MY

FACE IN THE DUST, I CONFESS O GOD THAT

I AM A REBELLIOUS LAWBREAKER IN THY SIGHT.

AND I PRAY THAT THOU WOULD HAVE MERCY UPON ME, THAT

THOU WOULD WASH ME RIGHT NOW WITH THE BLOOD OF

CHRIST AND MAKE ME WHITER THAN SNOW.

COME INTO MY HEART LORD JESUS AND FILL ME WITH

YOUR SPIRIT AND WRITE YOUR LAWS UPON THE FLESHLY

TABLETS OF MY HEART THAT I MAY DELIGHT TO KEEP THEM

BECAUSE I KNOW THAT I HAVE BEEN ACCEPTED IN SPITE OF

THEM AND NOT BECAUSE OF THEM, BUT BECAUSE OF YOUR

CROSS.

SO I REJOICE, O CHRIST, TO PLEASE THEE.

HELP ME TO LOVE THEE AND TO DESIRE ABOVE ALL ELSE

TO DO THOSE THINGS WHICH WOULD MAKE THEE HAPPY.

I PRAY IT IN THY NAME.

AMEN.

I HOPE YOU PRAYED THAT PRAYER WITH DR. KENNEDY

SINCERELY FROM YOUR HEART.

IF YOU DID, WE WANT TO SEND YOU BEGINNING AGAIN,

THE BOOK WRITTEN BY DR. KENNEDY FOR NEW

BELIEVERS.

IN THESE PAGES, YOU'LL LEARN HOW TO GROW IN YOUR

RELATIONSHIP WITH YOUR LORD AND SAVIOR, JESUS

CHRIST AS YOU LEARN ABOUT PRAYER, THE BIBLE AND SO

MUCH MORE.

IT'S OUR GIFT TO YOU, WHEN YOU WRITE TO THE ADDRESS

ON YOUR SCREEN OR CALL OUR TOLL-FREE NUMBER.

BE SURE TO ASK FOR BEGINNING AGAIN.

GOD BLESS YOU AS YOU DO.

DR. KENNEDY CLEARLY SHOWS THE JUXTAPOSITION BETWEEN

LAW AND GRACE THROUGHOUT THE BIBLE THAT SO MANY

PEOPLE OFTEN TIMES MISS. KNOWING THE

RELATIONSHIP THEY BOTH SHARE IS IMPORTANT TO

UNDERSTAND HOW TO FULLY LIVE YOUR LIFE FOR CHRIST.

ONE OF DR. KENNEDY'S MANY GIFTS WAS HIS ABILITY TO

MAKE COMPLICATED SUBJECTS EASILY UNDERSTANDABLE.

HE WANTED HIS HEARERS TO HAVE A FIRM FOUNDATION FOR

THEIR FAITH, AND HE BELIEVED THAT EVERY

CHRISTIAN COULD UNDERSTAND THE BASICS AND ANSWER

OBJECTIONS ABOUT THEM.

RECENTLY WE'VE PUT TOGETHER A SERIES OF HIS

STRONGEST SERMONS DEFENDING THE TRUTH OF THE

BASICS OF CHRISTIANITY AND PUBLISHED THEM IN A

BRAND-NEW KENNEDY COLLECTION HARDCOVER BOOK,

IT'S ENTITLED HOW I KNOW.

SOME OF THE TOPICS DR. KENNEDY DISCUSSES ARE:

HOW I KNOW THERE IS A GOD, HOW I KNOW THE BIBLE IS

THE WORD OF GOD, HOW I KNOW JESUS IS GOD,

AND HOW I KNOW CHRIST ROSE FROM THE DEAD.

WE WANT TO SEND YOU THIS IMPORTANT BOOK AS OUR

THANKS FOR YOUR GENEROUS DONATION TO THE ONGOING

WORK OF THIS MINISTRY.

SIMPLY WRITE TO US AT:

OR CALL TOLL FREE:

OR GO ONLINE TO:

EACH OF THE MESSAGES IN THIS BOOK DEALS WITH A

SUBJECT THAT SHOULD BE ESSENTIAL BIBLICAL

KNOWLEDGE FOR THOSE WHO PROFESS TO LOVE THE LORD

JESUS CHRIST, AS WELL AS FOR THOSE WHO ARE SEEKING

TO KNOW HIM.

AND WE'RE ALSO MAKING THESE MESSAGES AVAILABLE

ON A 4-DVD, OR 4-CD SET.

FIND THE TRUTH THAT WILL SOLIDIFY THE FOUNDATION

UNDER YOU, AND HELP BUILD A FOUNDATION FOR NEW

BELIEVERS- OR EVEN THOSE WHO'VE NOT YET COME TO

FAITH.

WE'LL SEND YOU THE HARDCOVER BOOK AND THE

4-DVD OR 4-CD SET HOW I KNOW AS OUR THANKS FOR

YOUR GENEROUS DONATION OF $50 OR MORE.

SIMPLY WRITE TO US AT:

OR CALL TOLL FREE:

OR GO ONLINE TO:

AT D. JAMES KENNEDY MINISTRIES WE ARE

STANDING FOR TRUTH AND DEFENDING YOUR FREEDOM.

I'M FRANK WRIGHT.

THANKS FOR JOINING US FOR THIS EDITION OF KENNEDY

CLASSICS.

WE'LL SEE YOU NEXT TIME.

TODAY'S PROGRAM IS AVAILABLE ON DVD

OR AUDIO CD FOR YOUR GIFT TO THIS MINISTRY

OF ANY AMOUNT.

PLEASE CALL, WRITE, OR LOG ON TO OUR WEBSITE TODAY.

THIS HAS BEEN A PRODUCTION OF

D. JAMES KENNEDY MINISTRIES

For more infomation >> Kennedy Classics - Grace and Law - Duration: 28:31.

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Why are you crying?

Why are you crying because of me?

Thank you for what you did

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How to paint mandalas with acrylics # 9 - Dreamcatcher - Duration: 10:38.

Hello, welcome to my channel

today we are going to paint

a dream catcher with the pointillism technique

and we're going to do it in a super easy way

I already have here the drawing previously made

then we will trace it directly on the canvas

I'm going to put the link for you to download this drawing

and so you already have and for you it is much easier

well, and I'm going to explain a little bit what tools we're going to use

the first, the main thing is a canvas, this is the size

30 X 20 centimeters

I have painted it in black

I painted it last night, the paint has dried, it's ready to paint

let's use gold paint

and

white pearl paint

these are the two colors that we are going to use

the tools we are going to use for the dots

they'll be

these punches

a brush for the smallest dots

a brush

super fine, the smallest size you can get

and

of the blue punches that I usually use

today we are going to use

the smallest

the one with the smallest balls

we are not going to use them today

so the dots are going to be

with these punches we will go combining

these sizes

ok

Come on, let's get started and I'll explain the first step.

well now what we have to do is with a pencil

white chalk or pastel

of those who paint very hard

Let's mark the whole drawing

but pressing

strong enough to be well marked

once we have all the drawing marked with the pencil

we turn around

and put it on top of the canvas

Let's use a little bit of scotch tape

to adjust it

and now with the help of something that is flat

we will go

passing it

for the whole drawing

now we take the paper off have to be marked

more or less fine

if there is any area that is not well marked

Let's take the pencil and re-mark it.

Good and we are going to start painting

Let's start with small dots.

in the middle

these are the sizes

of the tip of the punch that have the ones that I use

so

so that you know

which is the one I use at all times

I'll list them

the one with the smallest tip is going to be 1, 2, 3, 4, 5

6 the small point of blue

and 7

the tip a little bit bigger than blue

ok

with size 2

let's do

a dot

here

and now with size number 1

little dots

now we will use size number 3

for the dot

from here

and size number 2

to make the line

now a dot here

with size number 5

and three dots in decreasing form with the size number 4

and we ended with the number 2

now a dot with the size number 6

and dots

decreasing with size number 5

we end up with size number 3

now dots with size number 7

and decreasing dots with size number 6

and we end with the number 4

now dots with size 7

all around with the golden color

and now dots with size number 3

and now with size number 1

two dots

between two dots

now dots with size number 7

and now with size 6

we make dots in decreasing form

Dream catchers are instruments of power

of shamanic medicine

whose origin dates back to the American Indian tribes

according to the tradition

dream catchers help keep good ideas and pleasant dreams with us

as well as to protect the possessor

The time of dreams is influenced by good and bad energies

these last

are trapped by the net and dissipate through the central hole with the first rays of sun

"Let the spider web

catch your good memories and bad ones pass through the middle hole and fade away "

and now dots with the size number 1

now that the paint has dried

with a wet cotton swab

we are erasing all the lines of pencil

well guys, it's already finished

we have deleted all lines

now it would only be necessary to give it a coat of varnish

If you want

I'll give

because it is more protected

and nothing more

I hope you liked it a lot

that you do it at home that is very easy

remember that I am going to put the link

with the drawing so you can download it

in the video description

and

nothing more to say to you that

thank you very much everyone for watching my videos

and see you next time

see you soon

bye

For more infomation >> How to paint mandalas with acrylics # 9 - Dreamcatcher - Duration: 10:38.

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EPISODIO 1: ¡QUE NO SE TE QUEME EL ARROZ! - Duration: 7:44.

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LATEST INDIAN DEFENCE NEWS Chinese J-20 is operational now, India must speed up AMCA project. - Duration: 6:35.

China's J-20 Stealth Fighter Is Operational

According to a Chinese military spokesman, China's first stealth fighter, the Chengdu

J-20, has officially entered service with the People's Liberation Army Air Force.

First revealed in 2011, the J-20 is only the third stealth fighter to enter service with

any air force, after the F-22A Raptor and the F-35 Joint Strike Fighter.

A spokesperson for the Chinese Ministry of Defense, Senior Colonel Wu Qian, made the

announcement on September 28th in Beijing.

The aircraft was known as the J-20 during development, but the operational aircraft

is apparently called the J-20A.

This mirrors the development of the F-22 Raptor, which was labelled the F-22A Raptor when it

entered service with the U.S. Air Force in 2005.

China's development of the J-20A goes back to the late 1990s, when the government decided

to begin work on a large, twin engine fighter.

The first leaked photos of the aircraft appeared in December 2010, and the fighter was finally

sighted in early January 2011 at Huangtianba airfield.

U.S. intelligence expected the J-20A would enter service in 2018.

The J-20 has had a very public development period, with at least seven prototypes appearing

over the last six years, often with subtle but important improvements.

The fighter's nose shape, canopy, air intakes, and wheel doors were all altered and improved.

Engineers added radar-absorbent paint to further reduce the J-20's radar signature.

An infrared search and track sensor was added, which uses infrared cameras to detect, identify,

track and ultimately shoot at enemy aircraft with infrared guided missiles.

Yet another addition was a distributed aperture system (DAS), a series of cameras mounted

on the airplane that allows the pilot to "see" in all directions using a 4K cockpit display.

The only other fighter with a DAS is the F-35.

The official role of the J-20A is unknown, but it is most likely meant as a long-range

fighter.

The airplane stores all of its weapons internally to preserve its radar-evading shape, and has

three internal bays: one large bay for up to six PL-12 beyond visual range air-to-air

missiles, roughly the same as the American AIM-120 missile, and two smaller bays with

one short range air-to-air missile each.

J-20 fighters have flown with the 176 Brigade, a part of the air force's China Flight Test

Establishment, for approximately a year.

It's unclear what unit of the PLAAF the J-20A is operational with.

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