Let's see what makes a molecule chiral and how to find all of the chiral
centers. Hello everyone, I'm Melissa Maribel your personal tutor and let's start with
understanding what a chiral molecule is. If a molecule is chiral it means there
is no line of symmetry the left side is not the same as the right and the
molecules mirror image is different and nonsuperimposable meaning we cannot
perfectly align the molecules on top of each other. A molecule is achiral if
there is a line of symmetry within the molecule, the left side is the same as
the right side which is why it's achiral.
Let's do another example and see what molecules are chiral or achiral if we
were to cut the middle of each molecule we would see that the top and bottom
parts of this first molecule are not the same so there is no line of symmetry
making it a chiral molecule. However, the second molecule does have a line of
symmetry since the top and bottom parts of the molecule are the same making this
an achiral molecule moving on to chiral centers a chiral center is an
atom that is attached to four different groups, we represent a chiral center with
an asterisk. When an atom has a double or triple bond it cannot be a chiral center
since there are not enough groups. For example, this carbon is not a chiral
center because there are only three different groups and we need four
different groups for this to be a chiral center. Let's identify the chiral centers
in these two examples looking at this carbon we will see if there are four
different groups surrounding the central carbon we have OH this carbon chain, a
totally different carbon chain with an OH group and a hydrogen so both of these
carbons are our chiral centers note an achiral molecule can still have chiral
centers as shown here. This entire molecule does have a line of symmetry
and both parts are the same making it achiral.
In this example there are actually no chiral centers because there are two
methyl groups and remember all of the groups have to be different. Note: a
chiral molecule does not have to have a chiral center there is no line of
symmetry within this molecule making it chiral.
Okay to make sure you fully understand everything we just covered try these two
questions and we'll go over the answers in just a little bit. For question one
identify the chiral centers. To find the answer to question one let's check each
carbon and see if there are four different groups. Hmm nope not enough
groups not enough groups for the next carbon this carbon has one two three
four different groups so yes this is a chiral center. Next remember double or
triple bond will never be a chiral center so this one is not a chiral
center. This next carbon doesn't have enough groups the next carbon has one
two three and four different groups so yes this is another chiral center and
this end carbon is a common mistake it has enough groups but there are two of the
same groups our methyl groups but we need all four groups to be different so
this is not a chiral center. There are only two chiral centers in this molecule.
For question two label each molecule as chiral or achiral
To find the answer to question two remember we are looking for lines of
symmetry, if there is a line of symmetry within the molecule then it's achiral
like this first one is. Here is another hidden line of symmetry we can count the
number of carbons on either side and see that we can cut this molecule in half
and it would be the same since there are 1, 2, 3 carbons on the left and 1, 2, 3
carbons on the right making this molecule achiral. Now for the remaining
molecules there is no line of symmetry no matter how we try to cut them down
the middle they are never the same so these both are chiral.You can find other
helpful videos right here and if you would like additional homework help
tutoring or other resources you can find that all in the description box and
remember stay determined you can do this
For more infomation >> How to Find Chiral Centers & the Difference Between Chiral vs Achiral Molecules - Duration: 4:51.-------------------------------------------
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Driver 'Grateful To Be Alive' After Tree Smashes Moving Car - Duration: 1:27.
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Watch Live: Brett Kavanaugh testifies following Ford's questioning on sex assault allegations - Duration: 9:06:12.
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Laeticia Hallyday, un compte en banque secret intrigue les avocats de David et Laura - Duration: 2:47.
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大S汪小菲瑞士吃火锅庆祝八周年纪念日,素颜与路人合影皮肤超好 - Duration: 1:27.
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Adivina la canción! | Reto con Julie - Duration: 13:29.
Hi everyone, and welcome back to my channel
I'm with Julie again
Hi
And today we're doing a video playing "Guess that challenge"
My sisters are gonna play different songs
The first five seconds of every song
and then we have to guess which song it is
And whoever guesses it first, wins
So that we don't just yell out the name, we have to grab this bottle first to say what it is.
It has to be the name of the song, the artist, or continue singing that song
Because most of the time I don't know the artist or the song or..
Or the song, or anything.
I won
We're gonna start
We sang this song in the car, when we did that video
Whose friend is this? Not my friend
The bottle flew
This one didn't count because we both went for it and broke everything
Here you are
Ulises just got here
Ok well I hope you guys enjoyed this video
It's hot
Who won?
I knew I lost so..
Oh my battery died
This is like triple g and Canelo
If they're stealing the fight from me
Let us know if you'd like to see another video like this.
If you want me to do another video with Julie
Want me, Love me
To those that love me, I also love you
And to those that don't, go #$#@ %
And to those that don't, I also love you
But I want to real far
I want you... but far away from my life
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Mystery of the HUI finally unveiled - Ep 46 Sailing Luckyfish - Duration: 16:03.
In May, 2017 a group of men, women and children
from all over the US and many parts of the world,
came together in Fort Myers, Florida.
They all shared one thing in common.
An interest in Wharram designed sailboats.
I only flew in yesterday
And the day before I was travelling from Greece to England
And all yesterday flying here, so
Truly
Still a bit groggy
Ohhh. So you were in Greece with Spirit of Gaia yeah?
Yesterday was a 22 hour day.
Yes
I saw you sailing in
I cant believe that
I knew it was you
I looked down and I saw, I know
That boat
That must be Luckyfish
Thats amazing, yeah.
Well we came in about 7 or 8pm last night
It was about 5, 5:30
You were near the bridge
You must have been on our first bridge, yeah?
Yes, outside the first bridge
Sun out and its raining
Welcome to Florida
It was nice meeting you
Yeah, very nice
Good luck in everything you do
We'll see you tomorrow right?
Were going this afternoon
Are you going to be there?
Yeah, we are staying at the hotel
OK
The Best Western. Yeah, were there.
Good.
OK see you then.
Bye Bye
The first time I came across the word Hui,
was when we first arrived in the Caribbean.
Its a Polynesian word meaning gathering
and its roots go back 5,000 years
to Asia where it still means meeting
in Mandarin today.
In the case of a Wharram Hui
it means a gathering of double - canoes
and, the people that designed, built and sail them.
It was the prospect of meeting these folks
at a Hui in Florida,
that lead us to sail 1800 miles across the Caribbean and discover
what a Hui would mean to us.
Shall we dock or anchor?
Would it be better to go bow in first?
I think bow first, port side tie yeah?
Good job
OK at the front
These meetings have been going on almost as long as there have been Wharrams.
From the early ones in the mid 70s in England,
to Lake Neusiedl in Austria,
to Lake Ontario, Canada,
to New Zealand,
to Lakes in Italy, and,
for quite a number or years
right here in Florida.
Nice looking sail too
And so we found ourselves in Florida,
at the start of the hurricane season,
without a hurricane plan,
having catapulted ourselves into a sea of complete strangers.
It was a far cry from the normal
peace and solitude we are used to on Luckyfish.
But somehow, we had faith
this Hui would have all the answers.
First, we met everybody..
There was Tony from ScubaTony
the Scuba Diving company on Cozumel
Tony had flown in from Spain
to see Luckyfish before deciding to commission a Tiki 38
build of his own.
We met Mike from Michigan,
round the world sailors finishing he and his wifes
latest project
You got something to say?
I am excited to be here
a huge Tehini 51
Andy had flown in from California
to look at designs
to help him decide on which one for his own boat.
He also won the Communal Spirit award
This person in the
communal spirit of Wharramites everywhere
was happy to drink all the free booze he could get
on any boat that was there
and then, the next morning,
replensish all the booze
[CHEERS]
Andy
[APPLAUSE]
[LAUGHS]
Brandon and Danielle had driven over from nearby Sarasota.
They were a mine of local knowledge, refitting their Tangaroa at a nearby yard,
and extending a huge hand of hospitality to us.
We met reknowned professional boat builder David Halliday
from Boatsmith in Jupiter,
and learned about some big budget,
big Wharrams he was building in fibreglass.
We met fishing guide and sailing rig enthusiast
El Capitan Gerry who we will see a lot more of
in upcoming videos.
So thats what you use to make the videos?
Yeah, we just use cellphones. It works.
No GoPros or nothing like that?
We just bought one.
We are new to it.
We havent used that one.
We have got a drone and the GoPro
I use GoPro all the time
And it works really well
Really?
We would like to learn from you then.
Jimbo made a spectacular entrance,
singlehanded under spinnaker,
on his Narai 40
Huge
Le Sousa and his son Ian had driven in to meet some owners,
look at the boats and go out for a trial sail.
Casey and Shaun from Journey Island Style
spent 3 months cruising the Sea of Cortez on their
21 foot Tahiti Wayfarer outrigger
before building a second canoe,
and turning her into a catamaran.
Now they are rebuilding a 36 Tangaroa in Alabama.
Brent blew in from New Zealand,
via the Mississippi
and blew everyone away with a song
In true Polynesian fashion
he might be the closest thing we have today to an
actual Polynesian
Shaun: Hes a bloody Kiwi!
.[LAUGHS]
Hes also a Mississippian so we arent sure
exactly what program hes on
Hes going to teach us some Polynesian songs!
[CHEERS]
Do you want to learn one?
[YEAH]
So, obviously I am from New Zealand
Which does make me the closest thing you have to a Polynesian
[LAUGHS]
As crazy as that sounds
Obviously, New Zealand is one corner of the Polynesian triangle
I went to school
in New Zealand
I believe you have that here? School?
[LAUGHS]
It was good. I had fun. At school.
And part of going to school
was that we would learn to sing songs
in Maori, that is called Waiata
And the waiata we are going to sing
I learnt so long ago I have no idea what it means
[LAUGHS]
I think it means gathering of friends
But dont quote me on that or were in trouble
So, keep drinking
[LAUGHS]
because its going to get better
if we get really good we might go into thirds
but lets try and get it in one
So Im going to say the line
and you are going to
repeat the line to me
and if I remember it properly
we will keep going to the next line
is everyone clear on whats going on
Yeah !
Oh thank you sir
It has no...
Its not like...
I cant say its to the tune of Disneys Frozen
Because Disney Frozen didnt exist when the song was written
So, it goes like this
E toru nga mea (There are three things)
Nga mea nui (Very important things)
E ki ana (As stated in)
Te Paipera (Our tradition)
Tumanako (Hope)
Whakapono (Faith)
Ko te mea nui (And the greatest thing)
Ko te aroha. (Charity/ Love)
[APPLAUSE]
That was beautiful
I assume you are all aware
Aroha means Love
And we could all do with a little more love
[APPLAUSE]
Well done Brent
Hes the closest thing we got to a Polynesian
This boat was designed in memory of James' first voyage
across the Atlantic
it was in the little Tangaroa
its in the book, for people you have got the book
and it was 23 feet 6 inches long
and he sailed with these two lovely German girls
and a dog
and alot of books
across the Atlantic in 1956
So that is now, 61 years ago
So we designed the Mana
and it is exactly the same length
and so it is in memory of that, really
In fact it is exactly between the Tiki 21 and the Tiki 26
both of which are here
James would have loved to have been here
He is trying to write another book
His biography
It's 40% written so far
All the early parts are written
and the later parts, we will be working on
over the next year
and I will be helping him because
he has reached the stage when I joined his life
So, I can at least help him, because I was there
And thank you all for building boats
and being so enthusiastic about it
and having these wonderful meetings
and its been gratifying to see so many people
loving their boats and being here
[APPLAUSE]
The following day Zaya and Marge went to work
on our sail repair
while outgoing Hui organiser, Dan,
performed a boat re-naming ceremony
so not to raise the ire of Poseidon or Neptune.
.... this worthy vessel hereinafter for all time known as "Tortuga"
guarding her with your mighty arms
and ensuring her safe and rapid passage
throughout her journeys within your realm
To celebrate, we must
[HOOTS AND APPLAUSE}
Better do the bows
Not much!
Alright, get the cups!
Cups!
Over here Sir
Its a little warm
but what the hell
its booze
and then James joined us,
via Skype
and we wished him a Happy 89th birthday
The first thing I'd like to say is that
the weather is beautiful!
Cool, crisp, spring, sunshine
And I am told it is hot, sticky and miserable where you are
[LAUGHs]
Happy birthday to you
Happy birthday to you
Happy birthday dear James....
Well, that just about covers the 2017 Florida Hui,
Wait, do the ladies have chairs?
I thought they were doing a lap dance
who are they dancing on?
[CHEERING]
but before we get to the parties these Huis
are famous for,
Dan read a rather fitting eulogy to Skip Lichty,
one of the early Wharram pioneers
This year, we lost, one gentleman, Skip Lichty
And, in his memory I would like to read a very brief memorial
and then have a moment of silence
It is later than you think
The clock of life is wound but once
And no one has the power to tell when the hands will stop
At late or early hour
Now is all the time you own
The past a golden link
We cruise or dream of it
Not to escape from life But to prevent life from escaping us.
Go cruising now my friends,
Its later than you think
May fair winds
Calm seas
And bright sun
Follow you always
As you continue your sailing journeys
Through the universe
Now a moment of silence for Skip
Fair winds dear friend. Lets party.
[CHEERS]
Don't step back Mike
I'm going for a different camera angle here
[HOOTS AND MUSIC]
That. That's not on the next episode of Luckyfish
Yeah, Andy was right.
Some things stay at the Hui.
The Hui was supposed to end on a Sunday,
but the last boat didnt leave until Tuesday.
It was like meeting family you never knew you had
James Wharram summed it up 30 years ago
and his words are still just as relevant today
[MUSIC]
Before we leave you this week
wed like to give a shout out to Neil and Gail
who have placed Gleda,
their Tiki 38
on the market in Spain.
In true Wharram spirit,
Gleda is probably the most blogged Wharram construction ever,
with every construction hour and many of her sailing achievements
recorded and shared to the benefit of a great many folks.
The boat is listed on the Scott Brown Multihulls site.
There is a link in the description.
This is a great opportunity
for some-one wanting to go cruising straight away.
Dont forget to subscribe to our channel if you havent already
and thank you for watching.
-------------------------------------------
Congressional Elections Explained: What's at stake for this year's midterms? - Duration: 1:45.
Back in
The founding fathers set up that thing called Congress.
And there were some ground rules.
One, Congress would be split in two parts.
The House and the Senate
Two, the people in the House and the Senate would serve for different amounts of time.
And three, everybody would not be up for reelection
at the same time.
This was all so Congress would be
stable and productive.
Key word there: productive.
Jokes on the founding fathers.
Here's a quick civics refresher.
The House of Representatives has 435 members.
The Senate has 100 members.
If your business card says representative
you get to call the House home for two years.
If your business card says Senator, you get six.
And elections happen every two years on even number years.
Since members of the House serve two year terms,
they're always on their toes
And have to campaign to get the votes
to head back to DC every election year.
Senators are broken into three groups
Only one of those groups, so a third of the Senate,
is up for reelection each election year.
During the midterm elections this year
26 Democratic Senators are up for reelection.
Just nine Republican Senators are.
And Congress is majority red right now.
If Dems can steal a few Republican seats,
Congress could go blue.
If Dems lose any seats,
Republicans get to keep wearing the pants.
This is not a game of musical chairs
that either side wants to lose.
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My Queer Book Journey - Duration: 2:33.
The first time I read a queer book, I was seven years old.
I was looking through the shelves of my school's library, and I pulled out one called Heather
Has Two Mommies.
I remember standing there and reading it cover to cover.
When I finished it, I thought "Huh.
So that's a thing."
There was no moment of epiphany.
There was no sudden understanding of who I would be years from now.
There was just a door I wasn't aware had been closed, now--slightly ajar.
Almost ten years later, I was out and proud when my mother asked me if I had read Rubyfruit
Jungle.
When I told her that I hadn't, she replied with "And you call yourself a lesbian."
So I read it.
And I realized that my love of reading and my identity could intertwine.
One book lead to the next, and I could never quite slake my thirst for that representation.
I wanted to see myself in books like I never had before.
I searched for more, and when I couldn't find resources, I created them: the Lesbrary,
a compendium of reviews from dozens of readers around the world.
Other queer readers--from teenagers to middle-aged women--reached out to me, thanking me for
helping them access this texts that they desperately needed.
Another decade past that, I was able to connect to the Sooke school district over their SOGI
123 book list: a $5,000 grant given to the district to buy queer kids' books for every
age level.
As manager of the Children's Department at Russell Books, I helped them to select
texts for every school, squeezing as many books as possible out of that budget.
As the books came in, I laid them out in long rows, double-checking that all eighteen elementary
schools had the same bundle of books, that every counsellor had the titles they needed,
that the high schools had heavy boxes to bring into their libraries.
As I assembled those kits, I thought about all the kids who would be able to access the
stories that were so few and far between in my youth.
How many students would find themselves in those pages?
How many would gain the understanding to be a kinder, more accepting person later in their
lives?
During my time observing at Belmont, I noticed the books on display: my books.
The books I had selected and sourced and packaged.
Those queer books, proudly in the most prominent spot in the library.
Books about queer people of different ages, genders, and races.
Different genres.
Different reading levels.
Whether I become an English teacher or a teacher librarian, the inclusive library will be something
I bring with me.
I know the impact of reading a story that changes your life.
I'll seek to always create a library where every person belongs.
Where everyone's story can be told and respected.
Shelves packed with queer books and multicultural books and diverse stories of every kind.
A library of ideas, both on the page and in the community we create in our classroom.
A classroom with the door ajar.
And a library where everyone is welcome.
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Laeticia Hallyday, un compte en banque secret intrigue les avocats de David et Laura - Duration: 2:47.
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Man Utd news: Wayne Rooney wades in on Jose Mourinho vs Paul Pogba feud, Frenchman warned - Duration: 3:02.
Pogba had a game to forget in United's last outing, which saw the Red Devils suffer a 3-2 defeat to Brighton
The World Cup winner was critical of his team-mates' attitude at the Amex Stadium and insinuated that they weren't properly prepared for the match
"I will always try, I know I lost a lot of balls, that shouldn't happen for a midfielder," the France international told The BBC
"I try, I keep pushing, that's my personality. I know if I lose some balls I try to play it simple but sometimes when it's not your day, it's not your day
"I think they prepared [for] the game very well, they prepared much better than us
They really want to press, and stuff like this." Pogba's comments further fuelled talk of a rift between himself and manager Jose Mourinho, who is also seemingly at odds with United executive vice-chairman Ed Woodward
Rooney agrees with Pogba's statement, to a certain extent, but believes he must take it upon himself to ensure he's firing on all cylinders
"He is a fantastic player but he has to do it for himself," the former United and England striker told CNN World Sport
"If they're going to win the title, he'll be the main player in terms of them doing that
"You hear a lot of people saying Jose Mourinho needs to get the best out of him but he needs to do it for himself and prove he's at that level to help Man United
" Pogba's decision to publicly lambast his team-mates surprised many, including former United midfielder Gordon Strachan
"I find it very strange that Pogba, and it might have just been lost in translation mind, would come out when you're sitting in the dressing room potentially watching the TV," he told Sky Sports on The Debate
"How would you feel knowing fine well you tried you're but you've had a stinker? We've all done that
"Sometimes when you don't play well it looks like you're not trying. "If you're trying your hardest and someone is saying 'by the way, we're not trying
' I don't know how I'd react to that." Pogba and his team-mates return to action on Monday night, when they'll welcome Tottenham to Old Trafford
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Harry Potter Mystery Wand Full Size Blind Bags Unboxing Wow! - Duration: 6:05.
welcome to Ollivander's Wand shop hi we were sent by Rose McGruder to go get our
wands oh very good and what's the last name? imagine. imagine...and the first
name? I'm bug and I'm mama oh very good let's see what we can find I'lll be right back.
Bug and mama Imagine....oh yes here we go. W.I. fans what
we have today are the 12-inch mystery wands from Harry Potter
collect all nine mystery wands. the wand chooses the wizard mr. Potter. in these
packages it includes a mystery wand, one box and matching character 3d bookmark
and of the 9 mystery wands you can get luna lovegood, Nymphadora Tonks, Lord
Voldemort and the Death Eater wand. Oh scary or you
can get Harry Potter Hermione Granger Ron Weasley Draco Malfoy or Neville
Longbottom what do you think we're gonna get well
let's see and find out so bug which one are you hoping for I'm hoping for three
I'm hoping for Luna Lovegood I'm hoping for Harry Potter's and I'm hoping for
Hermione Granger's well I have two that I'm really hoping for and that would be
Ron Weasley and Neville Longbottom I'm really hoping I do not get the Death
Eater alright well let's get them open and see who we got
please Hermione Granger oh this is fancy you're very nice I don't know if it's
all of them say Harry Potter because that's the name of it or I actually
got Harry Potter it looks like it has a velvet casing very fancy and
how you don't know why I got it I think you got RonWeasley I think you've got
the one I wanted remember the wand chooses you ooh I love the detail on
this it feels just the right weight and I it feels really really rough against my
hands it has a curved detail like right here so you can grip your hands on it
okay we'll see if you can find your bookmark oh look at that oh that is
super cool it's a 3d bookmark he's moving his head side to side yeah I really like
that I love his hair blowing oh very cool Ron Weasley can you see how that
moves gives it the 3d look very cool even though it wasn't the one I wanted
it's still very cool I agree all right now to see which one I
got maybe you also got Ron we could be twins maybe let's open it and see
there's our box who did we get ooh I'm really excited please don't be
The Death Eater please don't be The Death Eater oh good you got mine! so I have
Luna Lovegood how pretty is this look at the richness of the wood grain that they
put on there I do think they're plastic but they have really real wood like feel
and look to them that is super cool that is a beautiful coloring it looks
like a broom I guess if you stand it that way it kind of does very nice okay
let's see where's my card all right oh she's beautiful Luna
Lovegood isn't that pretty I love it it's adorable very very nice
well there you have it our trip to the wand shop do you have a favorite wand
that you would like to get? these are super cool we did find ours at Walmart
and there's seven more to collect after these two that's our collection for now
make sure to LIKE comment share and subscribe and find us on Instagram we
imagine workshop and we'd like to invite you to wave on to our other videos
until next time
thank you for watching subscribe it's free
What can you Imagine?
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Brett Kavanaugh says he was 'basically' never a belligerent drunk - Duration: 1:40.
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Breaking News - What happened to Ryder Cup hero Victor Dubuisson? - Duration: 8:28.
Ou se trouve Victor Dubuisson? Where is the hero of Gleneagles? What has become of the man who could - should - have been sending French fans into ooh-la-la eruptions of joy at Le Golf National this week? Four years on from being hailed as Le Phenomenon, just one of the titles inspired by his barnstorming performance in Europe's triumph over the USA, the famously distant Dubuisson is further removed from the spotlight than even he would like
Bearing the actual physical scars of an operation intended to repair a serious inner ear problem, he has retreated into 'frustrated' inactivity that he openly describes as 'stressful'
Not that Dubuisson is very open about anything, of course. If you aren't aware of his reclusive streak by now, you've simply not been paying attention
This is a man who refuses to answer questions that stray within a mile of the personal, a supreme talent who may or may not have left school at 'ten or 12' - and may or may not have been abandoned by his parents at the same age
What we know for certain is that he hasn't hit a ball in anger since missing the cut in the Open de Espana in April
His season has been, to quote the man directly, 'f****d'. With the Ryder Cup about to tee off in his home nation, Dubuisson isn't even the ghost at the banquet
When he might have been the Face of French golf, he is in the shadows. Not certain to even tune in, so hurtful is it to watch others do what he cannot
'Because I can't play, I don't watch too much golf on TV,' said Dubuisson. 'It affects me
It frustrates me even more. 'Of course I miss golf. I've been doing this every day since I was little, that's why it's frustrating, not being able to play
'When you know that the season is f****d, it's very difficult.' That word, difficult, is used regularly in connection with a player who is popular enough with his peers - less so with tournament organisers and sponsors, who rely on the pros helping to generate publicity
That's never been Dubuisson's thing. Probably never will. Still, it obviously irks him when some get the wrong idea about his absence, as he revealed in an interview with Nice-Matin
Quizzed on whether he understood why some were questioning his desire to play, particularly in this enormously important year for France, Dubuisson said: 'I do not understand, no
'I know I represent a lot for things for French golf. But it can happen that you get hurt
'Like when someone is sick. Me, I got hurt doing my job. All athletes are injured at one time or another
' Specifically on the subject of missing the Ryder Cup, he said: 'You know, a career is very long, all players have problems from time to time
'And you're never safe from injury. I know that, in two or three years' time, people will not remember this
'I am extremely disappointed not to be able to play golf for such a long time, especially in the year the Ryder Cup is hosted by France
'I would have loved to give myself a chance to be part of the European team again
'But my health is a priority. I hope to return to play as soon as possible.' The crisis began last year, when a sinus problem made breathing difficult - and flying 'unbearable'
Not that he was overly focused in 2017, anyway, admitting that for half of the season: 'I spent almost 80 per cent of my time fishing
' Still, as he put together a strong close to the year, including finishing third at the Dunhill in Scotland, he admitted the Ryder Cup was 'always in the corner of my mind'
With that as motivation, he went in for an operation - the scars behind his left ear are the telltale sign - intended to solve the sinus issues
Taking up the tale, Dubuisson said: 'I had this accident when I came back from the Spanish Open, my eardrum was hurt on the flight home - it exploded
'I had to have an operation and can't fly any more. It started with a sinus operation last year that had consequences for the future
'I could hit balls but at the moment of impact it hurt me a lot. It would slow down my healing and affect my balance
'Yes, clearly it's frustrating. All season, I've been wanting to play.After eight years on the Tour, not playing is weird
'I still do my rehabilitation so I can hear normally. I have to be very careful
I cannot hear anything on one side. 'I have a medical exemption. I can't fly or go underwater for at least six or seven months
'Let's imagine I had broken an arm. I could have started again at the end of the season
But I've only played half a tournament.' It's sad to see such a fine talent sidelined by injury
Sadder still to hear his response to being told he still looked trim and in shape
'But I do not do much, to be honest,' said Dubuisson. 'It's just so stressful that I'm not gaining weight
And being unable to hear scares me.' Given his reputation for unpredictability, maybe he will surprise everyone by pitching up at the big show outside Paris
Smiling and shaking hands with well wishers and European Tour bigwigs alike. For all we know, his ear has healed and he's honing his skills daily, ready to recapture the form that made him such an unstoppable force at Gleneagles, when he took two-and-a-half points from three in a one-sided spanking of the Yanks
When he speaks of those magical three days in 2014, it is always with warmth, declaring: 'That will remain with me forever
' None who watched him in his pomp will forget just how good Dubuisson was. All are asking the same thing
Whatever happened to the Gallic genius with the D'Artagnan goatee and the swashbuckling style? 'Apparently he sacked his golf coach so he can get a fishing coach,' the website National Club Golfer
com reported one tour player saying anonymously this week. 'The ear thing is true, apparently, but he doesn't want to play golf
'There are stories of him turning up and then just going home, or leaving his clubs at airports as he can't be arsed waiting that extra 20 minutes for them
'One year he turned up to Abu Dhabi with no trousers and his clubs were left there from the Race to Dubai the previous December
He claims he is shy and really concerned with what people think of him. He is an enigma that is getting a little old
' Another player confirmed he had also heard stories of Dubuisson getting to airports then going straight home because 'he doesn't fancy it'
He added: 'I just don't think he enjoys golf and I'm not sure he ever has. I think he's just good at it
But beyond that it's difficult for me to give an opinion because I don't know him personally
' A third player added: 'I got on with him fine but didn't know him well. He's a legend really, just doesn't give a s**t
I'm a fan.' Well, we all are. The question is when will we see him again?
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The Why and Vision of Jen Y Insights - Duration: 1:35.
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Combat Debut: Marines' F-35B Strikes Taliban Target in Afghanistan - Duration: 3:19.
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Liberação Miofascial Manual e Instrumental ESCAPULOTORÁCICOS e TRAPÉZIO Fisioterapia Dr Robson Sitta - Duration: 6:08.
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BEST CHOCOLATE CHIP COOKIE RECIPE EVER (seriously) - Duration: 4:22.
hey everyone it's Dorothy from CrazyforCrust.com welcome to my kitchen
today we're going to talk about making chocolate chip cookies now there are so
many chocolate chip cookie recipes out there and I've made so many of them but
I finally found the absolute best basic chocolate chip cookie recipe one thing I
love about a basic good old chocolate chip cookie recipe is that you can use
it in so many different ways so once you have that base recipe you can change it
up to fit your needs you can make cookie cakes you can add different kinds of
chocolate chips you can add peanut butter cups those basic cookie recipes
are super important to have in your recipe box and this chocolate chip
cookie recipe is going to be the best one that you've ever tasted I promise so
let's get started making my favorite chocolate chip cookie recipe my
chocolate chip cookie recipe starts with something a little different than a lot
of the other ones out there melted butter I love using melted butter in
cookie recipes because combined with the brown sugar that I add it gives kind of
almost a toffee sort of taste to the cookie recipe this chocolate chip cookie
recipe starts with a half a cup of melted unsalted butter to that you're
gonna add a half of a cup of brown sugar and 1/3 of a cup of granulated sugar the
brown sugar adds some softness and they both add sweetness because these cookies
have Belted butter I don't even need to use a mixer I can just use a wooden
spoon to stir it up to that mixture you're gonna add an egg and you're gonna
add baking soda salt and vanilla mix that all up with your wooden spoon it's
super simple and comes together very easily then you're gonna add a cup and a
half of all-purpose flour stir that in until it makes a thick
again it's gonna be a little bit softer than a regular cookie dough recipe
because you're starting with melted butter not softened butter and now is
where you add your chocolate chips I love using dark chocolate chips or milk
chocolate use whatever you like I absolutely love to add a ton of them so
I use about a cup and a half of chocolate chips little tip if you have a
Trader Joe's near you I absolutely love their chocolate chips they're melty and
they stay that way so I highly recommend them hey once your chocolate chips are
in your cookie dough it's time to scoop them out I love using a cookie scoop
this is a basic 2 tablespoon confused scoop that I use for most of my cookie
recipes they sell these things in all sizes one tablespoon 2 tablespoons up to
a quarter cup so you can make small cookies you can make huge cookies but
what's amazing about these is that you have a cookie scoop all your cookies are
gonna be the same size so I highly recommend it now the one bad thing about
using melted butter in a cookie recipe it's that you have to chill the dough if
you bake these right now they would completely spread out and get super flat
I like nice thick soft pillowy cookies so in order for that we're gonna have to
chill it for a little bit use your cookie scoop and scoop out
tablespoons of cookie dough onto your cookie sheet because you're gonna chill
them you actually don't have to space them out right now just put them onto a
cookie sheet and pop them into the refrigerator for at least two hours now
I say chill for at least two hours and you really really do need to chill for
at least two hours but if you're in a hurry you can pop them in the freezer
for about 30 minutes he'll do about the same thing then spread them out to two
cookie sheets and bake them for about 9 to 12 minutes or until they're done you
know they're done when they've just lost that glossy Sheen on top that means
they're gonna be and soft and a little bit gooey that's
the way I like my cookies now if you like them super done and crunchy you can
just keep cooking them but I like them soft and gooey aren't these gorgeous
look how delicious they turned out they're perfect
and soft and pillowy and those chocolate chips are just still gooey and delicious
look at the chocolaty gooey
best chocolate chip cookies ever thanks you guys for watching today be sure to
follow my channel find all my recipes at crazyforcrust.com and eat something
sweet today
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Breaking News - What happened to Ryder Cup hero Victor Dubuisson? - Duration: 8:28.
Ou se trouve Victor Dubuisson? Where is the hero of Gleneagles? What has become of the man who could - should - have been sending French fans into ooh-la-la eruptions of joy at Le Golf National this week? Four years on from being hailed as Le Phenomenon, just one of the titles inspired by his barnstorming performance in Europe's triumph over the USA, the famously distant Dubuisson is further removed from the spotlight than even he would like
Bearing the actual physical scars of an operation intended to repair a serious inner ear problem, he has retreated into 'frustrated' inactivity that he openly describes as 'stressful'
Not that Dubuisson is very open about anything, of course. If you aren't aware of his reclusive streak by now, you've simply not been paying attention
This is a man who refuses to answer questions that stray within a mile of the personal, a supreme talent who may or may not have left school at 'ten or 12' - and may or may not have been abandoned by his parents at the same age
What we know for certain is that he hasn't hit a ball in anger since missing the cut in the Open de Espana in April
His season has been, to quote the man directly, 'f****d'. With the Ryder Cup about to tee off in his home nation, Dubuisson isn't even the ghost at the banquet
When he might have been the Face of French golf, he is in the shadows. Not certain to even tune in, so hurtful is it to watch others do what he cannot
'Because I can't play, I don't watch too much golf on TV,' said Dubuisson. 'It affects me
It frustrates me even more. 'Of course I miss golf. I've been doing this every day since I was little, that's why it's frustrating, not being able to play
'When you know that the season is f****d, it's very difficult.' That word, difficult, is used regularly in connection with a player who is popular enough with his peers - less so with tournament organisers and sponsors, who rely on the pros helping to generate publicity
That's never been Dubuisson's thing. Probably never will. Still, it obviously irks him when some get the wrong idea about his absence, as he revealed in an interview with Nice-Matin
Quizzed on whether he understood why some were questioning his desire to play, particularly in this enormously important year for France, Dubuisson said: 'I do not understand, no
'I know I represent a lot for things for French golf. But it can happen that you get hurt
'Like when someone is sick. Me, I got hurt doing my job. All athletes are injured at one time or another
' Specifically on the subject of missing the Ryder Cup, he said: 'You know, a career is very long, all players have problems from time to time
'And you're never safe from injury. I know that, in two or three years' time, people will not remember this
'I am extremely disappointed not to be able to play golf for such a long time, especially in the year the Ryder Cup is hosted by France
'I would have loved to give myself a chance to be part of the European team again
'But my health is a priority. I hope to return to play as soon as possible.' The crisis began last year, when a sinus problem made breathing difficult - and flying 'unbearable'
Not that he was overly focused in 2017, anyway, admitting that for half of the season: 'I spent almost 80 per cent of my time fishing
' Still, as he put together a strong close to the year, including finishing third at the Dunhill in Scotland, he admitted the Ryder Cup was 'always in the corner of my mind'
With that as motivation, he went in for an operation - the scars behind his left ear are the telltale sign - intended to solve the sinus issues
Taking up the tale, Dubuisson said: 'I had this accident when I came back from the Spanish Open, my eardrum was hurt on the flight home - it exploded
'I had to have an operation and can't fly any more. It started with a sinus operation last year that had consequences for the future
'I could hit balls but at the moment of impact it hurt me a lot. It would slow down my healing and affect my balance
'Yes, clearly it's frustrating. All season, I've been wanting to play.After eight years on the Tour, not playing is weird
'I still do my rehabilitation so I can hear normally. I have to be very careful
I cannot hear anything on one side. 'I have a medical exemption. I can't fly or go underwater for at least six or seven months
'Let's imagine I had broken an arm. I could have started again at the end of the season
But I've only played half a tournament.' It's sad to see such a fine talent sidelined by injury
Sadder still to hear his response to being told he still looked trim and in shape
'But I do not do much, to be honest,' said Dubuisson. 'It's just so stressful that I'm not gaining weight
And being unable to hear scares me.' Given his reputation for unpredictability, maybe he will surprise everyone by pitching up at the big show outside Paris
Smiling and shaking hands with well wishers and European Tour bigwigs alike. For all we know, his ear has healed and he's honing his skills daily, ready to recapture the form that made him such an unstoppable force at Gleneagles, when he took two-and-a-half points from three in a one-sided spanking of the Yanks
When he speaks of those magical three days in 2014, it is always with warmth, declaring: 'That will remain with me forever
' None who watched him in his pomp will forget just how good Dubuisson was. All are asking the same thing
Whatever happened to the Gallic genius with the D'Artagnan goatee and the swashbuckling style? 'Apparently he sacked his golf coach so he can get a fishing coach,' the website National Club Golfer
com reported one tour player saying anonymously this week. 'The ear thing is true, apparently, but he doesn't want to play golf
'There are stories of him turning up and then just going home, or leaving his clubs at airports as he can't be arsed waiting that extra 20 minutes for them
'One year he turned up to Abu Dhabi with no trousers and his clubs were left there from the Race to Dubai the previous December
He claims he is shy and really concerned with what people think of him. He is an enigma that is getting a little old
' Another player confirmed he had also heard stories of Dubuisson getting to airports then going straight home because 'he doesn't fancy it'
He added: 'I just don't think he enjoys golf and I'm not sure he ever has. I think he's just good at it
But beyond that it's difficult for me to give an opinion because I don't know him personally
' A third player added: 'I got on with him fine but didn't know him well. He's a legend really, just doesn't give a s**t
I'm a fan.' Well, we all are. The question is when will we see him again?
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