Saturday, September 30, 2017

Youtube daily report Sep 30 2017

Premier League: Ian Wright's top tips including Man United and Chelsea

STRIKERS have been the talk of the town so far this season, with Romelu Lukaku, Harry Kane and Alvaro Morata among those blazing a trail.

IAN WRIGHT may not be banging them in for fun anymore but the Arsenal and England legend still has an eye for goal; or more importantly who's going to be scoring them this weekend.

Here, Wrighty runs the rule over some choice games and offers his opinion on where punters' money should be going.

Talk about a baptism of fire for Roy Hodgson! Manchester City last week, United on Saturday and then it's Chelsea.

It's not getting any easier for the Eagles.

There were glimpses of Palace being more organised against City but in the end they still got stuffed.

Roy will be looking to get this trio of games out the way before his work in keeping Palace safe can begin in earnest.

Like City, United are on fire right now and I can see them getting another four goals here; If not more.

With City scoring goals left, right and centre United know they need another big win to keep pace.

There's very little between the two sides at present and every goal is likely count when it comes to the title race.

United have won 4-0 three times already this season so the 17/2 on another 4-0 win can't be ignored.

Lukaku has started exactly as you'd want a £75m signing to start.

Not only has he scored a load of goals but he's also silenced those questioning his link-up play and the first touch.

To be honest, no one inside the game was overly worried about that sort of stuff but it was in the media a lot and has now been put to bed.

It's no surprise that he's doing what he's doing and you can see that even when he's not playing well the side he's in will carve out chances for him.

That's why he's scored 10 goals in nine games and will help himself to a couple more this weekend.

He's the only player in my mind when it comes to the first goalscorer market and with Sun Bets going top price he looks good value even at 23/10.

This is such a good game, I can't wait to see how it pans out.

I think playing a day later in the Champions League might mean Antonio Conte's men struggle a bit more than City, who played on Tuesday.

Pep Guardiola's men are absolutely flying at the moment and I think this one is going to come down to the forwards.

With David Silva, Kevin De Bruyne, N'golo Kante and Tiémoué Bakayokoso all in the mix it's going to be a great battle in the midfield but I think it will come down to Alvaro Morata and his counterpart, Sergio Aguero.

It's going to be a great battle.

Morata is the new guy on the block but he has hit the ground running, while Aguero has being doing it for years now in the Premier League.

I think both men will get on the sheet but Morata is looking like he man most likely to open the scoring here and I'd definitely have a flutter at 9/2.

Chelsea did the double over City last year and from my experience when that happens you are even more fired up to go back and do well.

It's all about confidence and momentum so both sides will want to keep their foot in the neck of their opponents to lay down a marker in the title race.

I think it's going to be a tight one and I wouldn't be surprised to see a 2-2 draw at the Bridge, worth backing at 11/1.

Ian Wright fancies Chelseas Alvaro Morata to get the first goal against Man City.

The Brighton result will have brought Newcastle back down to earth after they picked up a head of steam.

They shouldn't be too disheartened though, as they were playing some good stuff and they'll get some chances against a Liverpool defence with a lot of questions to answer.

The boffins at Sun Bets tell me there has never been a Premier League game end 0-0 between these sides too so expect goals.

Liverpool aren't firing on all cylinders yet and Newcastle will be ready to pounce on a poor performance.

But if you're asking me to part with money then I'd have to go with Jurgen Klopp's men as on paper they are the much better side.

I think the 12/1 on a 3-1 away win is a tempting proposition, and Firminho looks big at 11/2 to grab the opener so my advice would be to back him.

Be lucky.

For more infomation >> #Premier League: Ian Wright's top tips including Man United and Chelsea - Duration: 6:18.

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Il principe Harry allo stadio, una bambina gli ruba i popcorn - Duration: 1:24.

For more infomation >> Il principe Harry allo stadio, una bambina gli ruba i popcorn - Duration: 1:24.

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Peugeot 308 Active 5drs 1.2 Turbo 110pk met navigatie - Duration: 0:51.

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Belen e Stefano, incontro fra carezze e caldi abbracci: foto scoop di Gente - Duration: 4:07.

For more infomation >> Belen e Stefano, incontro fra carezze e caldi abbracci: foto scoop di Gente - Duration: 4:07.

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Lʼallarme degli esperti: da Cagliari a Catania 33 località italiane sottʼacqua nel 2100 - Duration: 2:39.

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Gossip U&D, Luca-Soleil-Cartasegna: le ultime novità sul triangolo del momento | M.C.G.S - Duration: 5:02.

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Giảm 19cm mỡ bụng chỉ trong 9 tháng, nàng 9X đã "lột xác thành người khác" khiến ai cũng mê mẩn - Duration: 3:42.

For more infomation >> Giảm 19cm mỡ bụng chỉ trong 9 tháng, nàng 9X đã "lột xác thành người khác" khiến ai cũng mê mẩn - Duration: 3:42.

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Referendum Catalogna, le ragioni di Barcellona e quelle di Madrid - Duration: 6:58.

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SsangYong Rexton W - Duration: 1:07.

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Alto's Adventure Game Unlimited Coin Hack - Duration: 4:17.

Today in this Video, we are going to hack Alto's

Alto's Adventure An Android game, downloaded..

in millions on Google Play Store..

Let me show you first number of coins I have..13

I always come up with such Videos..If you like You must subscribe the Channel at end of Video

Open Android Setting..

Open Apps

Open Alto's adventure game.

Clear Cache and Click on Force Stop..

Close the window..

Open Rom ToolBox or Root Browser..Link Below

This is RootBrowser app..Requires rooted phone

Go to "Data>Data>Com...."

Go to "Data>Data>Com.noodlecake.altosadventure"

Open shared_prefs

Open com.noodlecake.altosadventure.xml file

Open with RB Text Editor..

Find coin value and Replace with 6 Digits desired number..eg.999999

Its all fun...by the way..

Click on Save Icon to Save.

Close Application and Open Game..

Now we have...999****

For more infomation >> Alto's Adventure Game Unlimited Coin Hack - Duration: 4:17.

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Cách Giảm Cân Hiệu Quả - 9 Thói Quen Xấu Khiến Bạn Thừa Cân - Duration: 6:40.

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Teens in South Korea

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Make Sulfuric Acid by the Copper Chloride Process - Duration: 8:28.

Warning: Copper salts are toxic.

Sulfur dioxide is a toxic gas.

Sulfuric acid and hydrochloric acids are corrosive.

Wear gloves and work outside or in a fume hood.

Greetings fellow nerds.

In this video we're going to demonstrate yet another way to make sulfuric acid.

Our key ingredient this time is going to be copper chloride.

As usual i need to crush your expectations.

This is far more labor intensive and costly than just buying sulfuric acid directly.

In fact for the amount of work put into this you can probably get a better return

by getting a minimum wage job and then buying the acid with your earnings.

As usual our objective is to explore the science.

So let's get started wasting valuable hours of our life.

First we need a solution of copper (II) chloride.

I have about 150g in 400mL of water.

This was made in a previous video using copper metal and hydrochloric acid and used as a printed circuit board etchant.

Now the mixture for printed circuit board etchant tends to have a lot of excess hydrochloric acid.

It can still be used in this video but to help see the chemistry i distilled off the acid first and then added clean water back in.

I'll explain further why i did this as the video progresses.

Anyway, now we need a source of sulfur dioxide gas.

The most efficient way to make it is to burn sulfur and pump the sulfur dioxide gas into the reaction.

I'm going to instead use a sulfur dioxide generator that uses a solution of sodium metabisulfite and drips in hydrochloric acid.

This is overall a more expensive way of making sulfur dioxide but i'm using it because it's more convenient.

You can burn elemental sulfur instead.

Now we simply lead the gas into the solution of copper (II) chloride with vigorous stirring.

I placed the tube slightly above the surface of the solution to prevent backflow.

Anyway, Copper (II) chloride is an oxidant and reacts with the sulfur dioxide to form a mixture of sulfuric acid, hydrochloric acid, and copper (I) chloride.

The copper (I) chloride precipitates out as this white powder you see suspended in the solution.

Now the reason why i removed the excess hydrochloric acid from the copper chloride solution earlier

is because in concentrated solutions of hydrochloric acid the copper (I) chloride actually redissolves again

as it complexes with hydrochloric acid.

There is little visual indication of the reaction progressing.

While there is some color change the solution is too dark to notice.

At this point you might be wondering if other copper salts will work.

Copper bromide works but the resulting hydrobromic acid will reduce the sulfuric acid in the later steps.

Copper iodide doesn't form stable copper (II) salts so that can't be used.

Copper sulfate by itself doesn't react in this way so you have to have add halide ions for this to work.

Overall copper chloride is the best copper salt for this process.

Although you may substitute it with a mixture of copper sulfate

and a molar equivalent of hydrochloric acid since it'll form copper chloride in solution.

Anyway back to our reaction.

Now we can't add unlimited amounts of sulfur dioxide.

The copper (II) chloride can only absorb a half molar equivalent before it's depleted.

At this point we can separate our sulfuric acid

but we can instead regenerate our solution by changing our gas tube and this time bubbling in air.

The oxygen in the air slowly reoxidizes the copper (I) chloride into copper (II) chloride.

It helps to heat up the solution to between 60 and 90 celsius.

As the reaction progresses the copper (I) chloride will dissolve and the solution will become homogenous.

Unfortunately this oxidation step seems to be the achilles heel of this process.

It's incredibly slow.

I needed to bubble air for a full day before it all dissolved.

This makes the process very impractical for actual amateur synthesis of sulfuric acid

unless you start with kilograms of copper chloride and are very patient.

The main advantage of this process is that it's fully catalytic.

Once you regenerate the copper chloride solution you can bubble in additional sulfur dioxide to make more sulfuric acid.

Afterward you can repeat the cycle with more air.

Eventually though there will be so much sulfuric acid that it interferes with the absorption of gases and slows down the process.

I ran about 3 cycles before i decided i had enough.

For the last cycle don't regenerate the copper chloride.

Instead, let it precipitate and cool to room temperature.

Then filter the mixture to remove as much of the copper (I) chloride as possible.

This another reason why i removed the excess hydrochloric acid at the beginning.

If the copper (I) chloride remained dissolved it would make our sulfuric acid recovery much harder.

Now we have a solution of sulfuric acid, hydrochloric acid and small amounts of copper salts.

To separate our sulfuric acid distill off the remaining hydrochloric acid

and boil down with the maximum hotplate temperature until nothing distills over.

With the hydrochloric acid completely removed the sulfuric acid solution will precipitate out copper sulfate

and copper chloride salts that have very low solubility in high concentrations of sulfuric acid.

Now filter our sulfuric acid to remove the nearly insoluble copper chloride and copper sulfate salts.

And there we have it, sulfuric acid made by the copper chloride process.

It's slightly blue due to some to some minor copper contamination.

If you want you can distill the sulfuric acid using the high temperature heating mantle i showed an earlier video

to get pure concentrated sulfuric acid.

As for the copper salts and the bulk copper chloride from earlier,

now that we have removed the sulfuric acid we can regenerate it again.

Copper (I) chloride will oxidize on air somewhat so don't be surprised when it changes from white to a green, blue or even brown color.

Anyway, mix all the copper residues in a flask.

The copper sulfate in the distillation residue will feed forward to help make more sulfuric acid in the next run

so you don't need to worry about it building up.

Anyway, now once you've gathered all your copper chloride, add the hydrochloric acid that was distilled earlier.

You may need to top up extra water as the sulfuric acid carries away a small amount in its formation.

Now bubble air through the mixture to regenerate the copper (II) chloride.

Once it's dissolved, you are now ready to reuse the copper chloride to make more sulfuric acid.

Overall, the process does work and is catalytic.

The only consumed reactants are sulfur dioxide, water and air,

and the output is sulfuric acid, with everything else being recycled back in.

The catalyst, copper chloride, is very easy to make.

And as long as you're careful the process is much safer

and less toxic than some of my other processes like the electrobromine process.

In the end though i only got about 96 grams of sulfuric acid out of the three cycles i ran.

I'm not sure it's worth it for the labor involved.

The slowest part, the air oxidation, really hampers the utility of this process.

In theory you could bubble in air while simultaneously bubbling in sulfur dioxide for a continuous process.

But since the air oxidation is so slow you'll still be waiting long periods of time.

Now i know some of you would suggest using hydrogen peroxide.

I actually already showed in a previous video that hydrogen peroxide can oxidize sulfur dioxide and produce sulfuric acid directly.

No need for copper chloride catalyst in that case.

The drawback of hydrogen peroxide of course is that it's more expensive than air.

Nonetheless, there may be improvements to the copper chloride process with different concentrations of reactants,

hydrochloric acid and different temperatures.

I'll leave the optimizations up to anyone that wants to explore this process.

I have enough sulfuric acid as is.

So that is how you make sulfuric acid by the catalytic copper chloride process.

Thanks for watching.

Special thank you to all of my supporters on patreon for making these science videos possible

with their donations and their direction.

If you are not currently a patron, but like to support the continued production of science videos like this one,

then check out my patreon page here or in the video description.

I really appreciate any and all support.

For more infomation >> Make Sulfuric Acid by the Copper Chloride Process - Duration: 8:28.

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How to Build a Teleporter with Aliens - Duration: 3:51.

Suppose we're working with aliens who live near Alpha Centauri to build a wormhole teleporter

so we can go visit them - for dinner, or interstellar diplomacy, or whatever. Of course we'll

need to be able to talk with them about what to make each side of the portal out of, how

big to make the various pieces, and so on. But since we've never been to Alpha Centauri,

and they've never been here, this is tricky – I mean, if you tell me to make you an

arc that's 300 cubits long, and I don't know what a cubit is, you'll probably get

an arc that's not exactly what you were hoping for .

So we'll have to build, from the ground up, an easily sharable way of communicating

about the universe, where distances and such are based on ideas, rather than specific artifacts

. We'd probably start with basic materials, you know, like how instead of sending a vial

with a chunk of lithium in it across interstellar space, we can just say "use the atom that

has 3 protons, 3 neutrons, and 3 electrons." Water would be "the molecule that's a

combination of one atom with 8 protons and two atoms with 1 proton." And so on.

Once we have materials down, we can do clocks – we just tell the aliens that if they take

the atom with 55 protons and 78 neutrons , make it emit a photon of light in a certain way

, and wait for that photon to oscillate 9,192,631,770 times: that's what we call one second.

Once we have clocks, we can do distances: just tell the aliens to see how far light

goes in one 299,792,458th of a second – that's what we call a meter.

But this is when we would run into a massive roadblock – literally. Pretty much the

rest of our communication about the universe requires knowing what mass is, and what we

currently call a kilogram isn't an idea we can just tell distant aliens, the way we

can say "the atom with 3 protons". A kilogram is just a particular lump of metal sitting

in a particular room in a particular place on our planet , and if you want to know how

many kilograms of say, antimatter, you have, you have to take it there and weigh them against

each other . In the very near future, we're going to

settle on a more sensible way of talking about mass, so instead of saying "in order to

build this teleporter you have to come to the part of earth with good cheese so we can

show you our shiny lump of metal," , we'll either be telling the aliens to just get a

pile of something like 21.5253873 septillion of the atom that has 14 protons and 14 neutrons,

or we'll tell them to weigh how much mass an atom or molecule loses after emitting a

photon of light that oscillates roughly 135.6392534 septillion septillion times each second. One

of these two concepts will be our new kilogram, and even though the pile of atoms option sounds

simpler in principle, it's actually kind of harder and more expensive to do in practice.

Whichever way it is, once we have our new way of communicating about mass as an idea

instead of an object, we'll be able to build our wormhole teleporter with the alpha centaurians

. And then we can bring them here to earth, have dinner, and afterwards, show them the

chunk of metal that used to be THE THING that we used to talk about the mass of all other

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For more infomation >> How to Build a Teleporter with Aliens - Duration: 3:51.

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Watch the Trailer

For more infomation >> Watch the Trailer

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LATEST INDIAN DEFENCE NEWS Chinese J-20 is operational now, India must speed up AMCA project. - Duration: 6:35.

China's J-20 Stealth Fighter Is Operational

According to a Chinese military spokesman, China's first stealth fighter, the Chengdu

J-20, has officially entered service with the People's Liberation Army Air Force.

First revealed in 2011, the J-20 is only the third stealth fighter to enter service with

any air force, after the F-22A Raptor and the F-35 Joint Strike Fighter.

A spokesperson for the Chinese Ministry of Defense, Senior Colonel Wu Qian, made the

announcement on September 28th in Beijing.

The aircraft was known as the J-20 during development, but the operational aircraft

is apparently called the J-20A.

This mirrors the development of the F-22 Raptor, which was labelled the F-22A Raptor when it

entered service with the U.S. Air Force in 2005.

China's development of the J-20A goes back to the late 1990s, when the government decided

to begin work on a large, twin engine fighter.

The first leaked photos of the aircraft appeared in December 2010, and the fighter was finally

sighted in early January 2011 at Huangtianba airfield.

U.S. intelligence expected the J-20A would enter service in 2018.

The J-20 has had a very public development period, with at least seven prototypes appearing

over the last six years, often with subtle but important improvements.

The fighter's nose shape, canopy, air intakes, and wheel doors were all altered and improved.

Engineers added radar-absorbent paint to further reduce the J-20's radar signature.

An infrared search and track sensor was added, which uses infrared cameras to detect, identify,

track and ultimately shoot at enemy aircraft with infrared guided missiles.

Yet another addition was a distributed aperture system (DAS), a series of cameras mounted

on the airplane that allows the pilot to "see" in all directions using a 4K cockpit display.

The only other fighter with a DAS is the F-35.

The official role of the J-20A is unknown, but it is most likely meant as a long-range

fighter.

The airplane stores all of its weapons internally to preserve its radar-evading shape, and has

three internal bays: one large bay for up to six PL-12 beyond visual range air-to-air

missiles, roughly the same as the American AIM-120 missile, and two smaller bays with

one short range air-to-air missile each.

J-20 fighters have flown with the 176 Brigade, a part of the air force's China Flight Test

Establishment, for approximately a year.

It's unclear what unit of the PLAAF the J-20A is operational with.

For more infomation >> LATEST INDIAN DEFENCE NEWS Chinese J-20 is operational now, India must speed up AMCA project. - Duration: 6:35.

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[The 6th birthday of Star stable online] → Review of the game since 2011 ← - Duration: 4:15.

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Rubik's Cube Magic - Solving in a Second by Pranav J Pillai - Duration: 0:57.

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Cooking with Cast Iron: Yes, You Can Use a Little Soap - Duration: 3:16.

Lynne Rossetto Kasper: I recently downsized and let me tell you, scaling back my kitchen

of thirty years was a painful process.

My good knives made the cut, my big colander, my forty year-old wok, and my cast iron pans.

Now, as great as they are, there are a lot of questionable myths about cast iron cookware.

Well, to separate fact from fiction, our contributor Noelle Carter went to J. Kenji López-Alt,

Managing Culinary Director of Serious Eats and author of "The Food Lab" column.

Noelle Carter: So, cast iron--it's popular and, while it has a lot of fans in the food

world, it can be mysterious and, well, intimidating.

J. Kenji López-Alt: The issue that comes up with it, is maintaining the seasoning which

is the layer of polymers that form when you heat oil in it and that's what gives a cast

iron pan its non-stick properties and what makes it such a good surface for cooking on.

The general idea is that acidic foods will wreck your seasoning.

This is actually not really the case.

The seasoning is actually pretty tough.

It's a polymer that ends up filling in the little gaps and holes in the bottom of your

pan giving it a smooth surface.

So cooking acidic foods in it will not really strip that.

I wouldn't recommend cast iron as a pan to cook like a six-hour long tomato source or

something like that.

But, if you're going to sear a steak or a chicken breast and then you want to make a

quick pan sauce, you can do that just fine.

Soap will get rid of oil, but it won't break down that seasoning.

Rinse it.

Put it back on the stove top.

You don't want it to sit wet because that will cause it to rust, so once you're done

cleaning it, you just throw it back on a burner and let that excess moisture cook out until

the pan is a little bit hot and then rub a thin layer of oil into there with a paper

towel.

Noelle Carter: Let's say that I'm at a garage sale and I run across a really good-looking

cast iron pan, is there anything that I should look for before I buy it?

J. Kenji López-Alt: If you can find a pan that is polished, smooth, and shiny and has

that nice satiny luster to it that obviously someone has already taken the time to clean

it and season it for you, then you're really lucky.

If, on the other hand, you find a pan that has something that is tarnishing or rust,

often those pans are still quite good.

What you really want to look for is any kind of pitting or warping in the metal, because

older cast iron was a little bit thinner than modern cast iron and with repeated use could

get warps.

It would sag in the bottom or bulge out, sometimes even crack.

Noelle Carter: Do you have any favorite dishes you like to cook in cast iron?

J. Kenji López-Alt: If I'm cooking indoors, I can't think of a better way to cook a steak.

You place a steak in there, you get a better sear than you get out of anything, pretty

much.

I roast whole chickens in it.

It's great because it can go from the stove top to the oven.

I make bread and pizza in mine.

Noelle Carter: Pizza?

J. Kenji López-Alt: Yeah.

One recipe I have that I really enjoy is a no-knead pizza where you basically mix together

the dough and just dump it into the cast iron pan that has a little bit of olive oil in

it.

Then you just let the dough sit there, and it fills up the pan to the edges and rises

a little bit.

Then you just top it and throw it in the oven and it comes out like a deep-dish pan pizza

with like really sort of crispy almost like fried in olive oil focaccia-type edges.

If you're looking for brown and crispy, then the cast iron pan is a great way to get there.

Noelle Carter: It can't be beat.

For more infomation >> Cooking with Cast Iron: Yes, You Can Use a Little Soap - Duration: 3:16.

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Je me créer un MSP! -ChatonPetshop TV- - Duration: 3:11.

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[Tuto pâte polymère FIMO] Figurine Coccinelle : étape par étape 🍄 - Duration: 9:02.

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Top 10 Activity Cubes '17

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Masany Ki Grmi Pr Brf Jeasa Aser Kerny Wala Nuskha || Ehtilaam Aur Qatry Ana Bnd || - Duration: 3:47.

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THF:மருங்கூர் - சங்ககால நகரம் - Duration: 6:16.

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How to Build a Teleporter with Aliens - Duration: 3:51.

Suppose we're working with aliens who live near Alpha Centauri to build a wormhole teleporter

so we can go visit them - for dinner, or interstellar diplomacy, or whatever. Of course we'll

need to be able to talk with them about what to make each side of the portal out of, how

big to make the various pieces, and so on. But since we've never been to Alpha Centauri,

and they've never been here, this is tricky – I mean, if you tell me to make you an

arc that's 300 cubits long, and I don't know what a cubit is, you'll probably get

an arc that's not exactly what you were hoping for .

So we'll have to build, from the ground up, an easily sharable way of communicating

about the universe, where distances and such are based on ideas, rather than specific artifacts

. We'd probably start with basic materials, you know, like how instead of sending a vial

with a chunk of lithium in it across interstellar space, we can just say "use the atom that

has 3 protons, 3 neutrons, and 3 electrons." Water would be "the molecule that's a

combination of one atom with 8 protons and two atoms with 1 proton." And so on.

Once we have materials down, we can do clocks – we just tell the aliens that if they take

the atom with 55 protons and 78 neutrons , make it emit a photon of light in a certain way

, and wait for that photon to oscillate 9,192,631,770 times: that's what we call one second.

Once we have clocks, we can do distances: just tell the aliens to see how far light

goes in one 299,792,458th of a second – that's what we call a meter.

But this is when we would run into a massive roadblock – literally. Pretty much the

rest of our communication about the universe requires knowing what mass is, and what we

currently call a kilogram isn't an idea we can just tell distant aliens, the way we

can say "the atom with 3 protons". A kilogram is just a particular lump of metal sitting

in a particular room in a particular place on our planet , and if you want to know how

many kilograms of say, antimatter, you have, you have to take it there and weigh them against

each other . In the very near future, we're going to

settle on a more sensible way of talking about mass, so instead of saying "in order to

build this teleporter you have to come to the part of earth with good cheese so we can

show you our shiny lump of metal," , we'll either be telling the aliens to just get a

pile of something like 21.5253873 septillion of the atom that has 14 protons and 14 neutrons,

or we'll tell them to weigh how much mass an atom or molecule loses after emitting a

photon of light that oscillates roughly 135.6392534 septillion septillion times each second. One

of these two concepts will be our new kilogram, and even though the pile of atoms option sounds

simpler in principle, it's actually kind of harder and more expensive to do in practice.

Whichever way it is, once we have our new way of communicating about mass as an idea

instead of an object, we'll be able to build our wormhole teleporter with the alpha centaurians

. And then we can bring them here to earth, have dinner, and afterwards, show them the

chunk of metal that used to be THE THING that we used to talk about the mass of all other

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