Warning: Diethyl ether is highly flammable.
Sodium is a reactive flammable metal.
Fire safety protocols must be in place.
Greetings fellow nerds.
In an upcoming video i'm going to be making grignard reagents and performing grignard reactions.
Now grignard reagents are notoriously sensitive to water, reactive impurities, as well as air.
So before we begin we need to dry and purify our solvent diethyl ether.
So here is our diethyl ether.
This particular batch has been recovered from multiple experiments
so it's full of impurities including water, organic peroxides, small amounts of alcohols, esters,
halogenated compounds, acids and so on.
In fact if you look at it very carefully you can see droplets of water in the bottom.
Let me see if can zoom in for you.
As you can see this is not good solvent and would certainly ruin our grignard reactions if we used it.
Now the first step in purifying it is to add in some potassium hydroxide.
I'm using about 30g for my 500mL.
This will absorb water and highly polar impurities like alcohol as well as react with any acids and neutralize them.
As you can see this ether is so impure that the reaction with potassium hydroxide is generating enough heat to boil it.
Now for the most part this shouldn't happen with most sources of ether.
Just mine happens to be grossly impure since it was recovered from other experiments.
Chances are very little will happen with your ether.
Anyway, let this sit for a few hours until stops bubbling.
Now we add in a stir bar and let the mixture stir overnight to remove most of the water and polar impurities.
This will also give it time to destroy the halogenated impurities as well.
You might be wondering if you can use sodium hydroxide,
you can certainly use it but i prefer potassium hydroxide because when it absorbs enough water
it actually phase separates out of the ether into a seperate layer.
You can actually see that layer if you look closely.
Sodium hydroxide also separates, but it forms a thick goo which doesn't stir very easily.
An easily stirred layer tends to work faster than a thick goo.
Anyway, I'm going to let this stir overnight.
I forgot to film it here but i also stoppered the flask with a glass stopper to prevent ether evaporation.
So here we are the next day.
You can see most of the impurities have been pulled out by the potassium hydroxide
and some of it has turned brown due to various condensation reactions initiated by the potassium hydroxide.
Good thing it's all separated into another layer.
We now simply decant our ether into a new container.
Now for some very easy grignard reactions, this ether is pure enough and dry enough as is.
But to improve reliability i'm going to go a step further and destroy the remaining impurities with sodium metal.
Just get about 10g of sodium metal and cut it up into small pieces.
Then add them directly to the ether.
You can see it start to bubble as the sodium reacts with any remaining water and impurities and generates hydrogen gas.
i'm going to loosely stopper the flask with a plastic stopper so the hydrogen can still squeeze out
and escape but keep most of the ether vapor in.
You might wondering why I didn't add sodium the first time around and went with potassium hydroxide at the beginning.
Two reasons actually, one is cost.
Potassium hydroxide is cheaper than sodium metal and for an amatuere chemist like me using less sodium is always preferable.
The second and bigger reason is safety.
This is a lot of water.
If this amount had reacted directly with the sodium then it would likely have exploded.
Ether is extremely flammable and igniting it with a sodium explosion would have likely started an ever bigger fireball of burning ether.
In the past, there have been cases of scientists being killed after being engulfed by fireballs of burning ether.
So to avoid that i removed most of the water first with potassium hydroxide before going on to using sodium to finish it off.
Anyway, i let this sit overnight to react.
Here we are the next day.
The bubbling has stopped and the sodium is becoming discolored as it starts destroying other impurities.
At this point to help it along i'm going to drop in a stir bar and let the mixture stir on my magnetic hotplate stirrer.
Looking back, there was no point in letting it sit until the bubbling stopped,
so you can just add the sodium metal and begin stirring right away unless it's boiling too much.
Anyway, i left mine stirring for another day.
And here we are the next day.
The flask has become cloudy as the sodium destroys more impurities causing them to precipitate out.
The stir bar knocking around the sodium is also chipping off whatever impurities reacted with the sodium and solidified.
I'm now going to replace the plastic stopper with a greased glass stopper and completely seal the flask from air.
We want it sealed now so air and moisture doesn't get in and waste the sodium before it has a chance to destroy the remaining impurities.
A plastic keck clip should be applied so on the off chance it's still bubbling
and the pressure does become great enough to pop off the stopper,
it won't go flying away and possibly smash something else of value.
Keep stirring it now for as long as needed to destroy all the impurities.
You might be wondering how to tell and for professional chemists they add in an indicator which is benzophenone.
Benzophenone reacts with sodium to form a green, blue, red or even purple solution
once all the water and reactive impurities are destroyed.
The color is dependent on the solvent.
Benzophenone in ether tends to form red or purplish colors.
Unfortunately for us amateur chemists getting benzophenone is not easy so we're going to need another indicator.
Interestingly enough we can use the sodium metal itself.
Right now it's all covered in sodium oxides, hydroxides and other impurities and everytime it gets hit by the stir bar some of these are knocked off.
The sodium metal then quickly reacts with more impurities and becomes covered again.
But once all the impurities are destroyed the sodium will no longer react.
After that point, rather than getting dirtier as time progresses, the sodium will actually get cleaner as it gets knocked around.
And then something fun happens.
And here we are after a week.
The sodium cleaned up to the point that it started cold welding together into this nice shiny sphere.
It's at this point that we can say all the reactive impurities have been destroyed.
If they hadn't then the sodium would quickly tarnish again.
Now we setup a simple distillation apparatus and gently distill off the diethyl ether.
Remember to use thoroughly dried apparatus so we don't reintroduce water contamination into our ether.
Now i know spending over a week to purify diethyl ether seems excessive but as said before this batch was highly contaminated.
Ether usually only takes a couple of days to purify.
By the way you might be wondering how this sodium sphere is so large, as I only started with a small amount of sodium.
I found out later that this sphere was hollow.
It was filled with ether as well as particles of the impurities that had been knocked off earlier.
Once i squeezed out all the ether the lump left over was much closer to the original quantity of sodium i used.
You may also be wondering why i didn't use my favourite drying agent, molecular sieves, and used sodium instead.
Molecular sieves only remove water, but all the reactive impurities are still there and would still kill our grignard reaction.
Sodium drying is still the best way to purify grossly impure diethyl ether.
Anyway, after all the ether is distilled we now have a batch of fresh, purified, and dried ether which is perfect for use in grignard reactions.
I'm going to use this right away, but if you're going to store it then i reccomend storing it over molecular sieves
or sodium metal to destroy any peroxides that may form or any moisture it absorbs from the air.
Anyway, as said before, I'll be using this for grignard reactions.
Thanks for watching.
For more infomation >> Purifying and Drying Diethyl Ether For Grignard Reactions Using Potassium Hydroxide and Sodium - Duration: 7:56.-------------------------------------------
Mary had a little lamb with Lyrics| +More Nursery Rhymes & Kids Songs lullaby for children kids baby - Duration: 2:08.
Mary had a little lamb with Lyrics| +More Nursery Rhymes & Kids Songs lullaby for children kids baby
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Crazy $4,000 Dream Gaming Setup And Computer Unboxing 2018 - Giveaway and 1k Q&A - Duration: 10:18.
all right so if you want to enter the giveaway for this gaming keyboard this
game keyboard this gaming headset this mousepad and this mouse all you need to do is
turn notifications on. Leave a like on this video share subscribe and leave a
comment down below and make sure your active on my channel alright I hope you
guys enjoyed this video and all right before we start this video we're gonna
have a quick Q&A and MVP++ winner by the way most of these
questions came from the discord so join the discord right now it's in the
description join it right now there's giveaways and other stuff there and
you'll be notified way better than on YouTube alright let's get into this
video first question comes from KeoTheSavage. How did you come up with the name
Hamzah and when will you do a face reveal a face reveal at 1 million subs so hit
that subscribe button right now so we can hit it with in 2018 and how do I
come up with the name Hamzah well my parents did actually and the next
question comes from 57 he asked what specs are your PC? You can
figure that out in this video doublerod says xdxd face reveal now kid. Nope you
gotta wait until 1 million who says, says what is your second favorite minecraft
server there is no other minecraft server unless if I make one then join
mine. Have you ever used hacks? Of course not. YT Nicholas C G says recording
software? I use OBS Cryptorr_A says race reveal or what PC equipment
you have a race reveal at 10 million PC equipment in this videos spipuppy says
do you like potatoes of course zoop gaming says do eat water if you don't
why and I love this comment because of emojis on there that's great uh and of
course I eat water blurry says are you my dad yes how old are you 42 yes? No are
you a girl no I mean yes do you have any advice for MC youtubers or gaming
youtubers in general upload consistently yeah. Do you like sleeping? I do. Of course
I do it's like eating a sleeping or basically
my like favorite things to do can you adopt me? Of course
do you like 18 2018 so far? yes if you start to go bald when you do a comb-over
or accept baldness? I might pull like a FaZe banks and wear hat all the time
what kind of pizza do you like another question with zoop gaming I like
chicken and pineapple you know I had a 360 no-scope dab scope roll scope scope
be loved being loved just okay do you like pineapple on your pizza yes no no
no yes yes yes what is your favorite food
fettuccine alfredo or what is your favorite color pink what is your
favorite hypixel game blitz survival games on a scale of one to ten what is
your favorite color in the alphabet? true and this is the MVP++ winner and
let's get into the video. Lets get into the unboxing. I geuss we just start right here. Intel inside
ibuypower and then basically all that personal information on that side. okay. Cool. Look at that. Oh my goodness
I bought a couple things like a keyboard mouse pad mouse Stuff that I'll be giving all that
away all right oh my god so this is a case I got P7-C1
Lets just set that down right there. look at that that's the case if you want to read that
go quick and publicize go ahead any cool air cool cool all right so this
outfit I could get this out of the box all right kick this box out of the way
and by the way I'm gonna show you this like extra parts over there like
snowball mouse old keyboard mouse pad that's in there oh yeah like I said
school stuff in here and the keyboard that I'm using right now cool all right
now let's look in this case at this box.
Oh
project seven exploring the unknown. what's next?
that's sick now these are all the stats the stats. The specs pause and take
a look at that cool all right Now let's open this thing up. Oh my goodness.
all right so yeah how we can open this up this is this
I don't know open that in a second. That might be the power stuff? oh my goodness
so that's computer I think you're gonna have to give me another second while you
take that out but yeah so after we take that off. Take a look at this oh my god iBuyPower
Intel Core i7 seventh gen Aerocool
it's got one two three four right there. so yeah. you got the power you got all
that stuff right there the back of it look at that
that's the motherboard I think so this is it oh it's too like a 360 brb
so this is it starting here we got iBuyPower and intel Core i7. The back we
got all this get this power right there and then we can see the inside which is
probably what you guys are waiting for from the beginning so yeah. Let me read this
real quick and I'll be right back. Alright let's get that satisfying peel off real quick
And now we can see the beast that's inside here.
So apparently it's easier than I thought
so it's the bottom of the case all right so we start off with a graphics card. EVGA
a Geforce GTX 1080 superclocked I'm pretty sure um yeah that's pretty sick
Thermaltake liquid cooling there's some fans for that we got we got some sick
cabling we got red and black um we did the Elite build package so that's great
that's quite sick we have these two fans uh this is a motherboard and it's pretty
sick and yeah
Of course the powersupply and everything. Full specs would be in the description so if you
want to read that but yeah this is pretty much a beast
yes so let's get it started and also let me show you some monitors
that work we're dealing with you got the two Acer 24 inch monitors 144 Hertz one
millisecond response time 1920 by 1080 oh yeah it's pretty pretty cool man
like yeah okay cool let's get into it alright so this is everything that they
gave me this is like extra stuff if I want to install anything this is the RGB remote some
thermal paste all the EVGA everything this is pretty sick um bunch of stuff
that's cool there's like one for each room but yeah this is sick and now
we have basically everything set up. right so
this is the computer basically everything is set up
I'll fix some cable management stuff later but like it's not even that bad there's
the inside it'll look way cooler in a few seconds especially with that RGB remote you know lets just get into it I geuss
it all right this is the final setup. this is it all right here you
got the keyboard you got the mouse the Corsair you probably can't see we have
the PC itself
1080 liquid cooling everything in there 16 gigs of ram. we have the PC itself
right here the case got our headphones and this is basically how the setup
looks got both monitors both 1920 by 1080 Full HD 1 milisecond
response time 144 Hertz blue snowball this is all it yeah just look at that
that is beautiful alright that was the video hope you guys
enjoyed click at the top right to support me on patreon click the bottom
right to subscribe and click on the left to watch one of my videos hope you guys
enjoy the video see you guys any another one hopefully. Bye <3
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Al Bano: «Fare musica è come scopare» | K.N.B.T - Duration: 17:26.
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Isola dei Famosi 2018 2^ puntata: svelati due nuovi concorrenti | Wind Zuiden - Duration: 3:30.
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7 Mythen über Cholesterin 2 - Duration: 6:15.
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Life Perspective | PLUS SIZE INTIMATE CLOTHING – BE THE HEAD TURNER - Duration: 8:01.
PLUS SIZE INTIMATE CLOTHING – BE THE HEAD TURNER
Intimacy.
Doesn't the word itself sound exciting?!
Yeah, we all want to have that special person in our lives for whom we can dress up and
look gorgeous.
But wait a minute.
Is it always about looking good for someone else?
No right?
The fact is whenever we dress up, we might assume that we are dressing up to please someone
else, but deep down there, we know that we are dressing up for ourselves and because
we want to look good and attractive.
Now, let us break all stereotypes and accept the fact that it is nothing different for
women with a more voluminous body.
Plus Size Intimate ClothingThat's the reason why you have companies that offer plus size
intimate clothing nowadays.
You won't need to think twice about your special days and nights if you are aware of
these companies.
What are the kinds of intimate clothing that are available nowadays?
If you are looking for plus size intimate clothing, the world awaits you.
Let us take a look at the different choices you can make when it comes to buying plus
size intimate clothing.
* Plus Size night wears: you get fancy plus size night wears including nighties and gowns.
You can also opt for short dresses that are pretty comfortable and sexy at the same time.
You get them in different designs and colors.
* Plus size costumes: have some naughty ideas for the night?
Perfect clothes for such occasions are ready for you.
You can get different costumes in different sizes that make your night fun and exciting.
* Costume accessories: a very uncommon thing that is talked about but equally important,
costume accessories are pretty necessary for completing your intimate look.
You get panties, shoes and boots, wigs and romantic gifts when it comes to accessory
shopping.
* Hosieries: you don't need to worry about the lingerie you are going to buy.
You get different choices starting from body stockings, body shorts to G-strings and thongs
that make them go crazy for you.
The best part about these companies is that they have clothes for all of us.
You might be a new buyer or a demanding expert, the companies satisfy all its customers.
You get clothes in different ranges and you can choose the clothes according to your design
and color preferences as well.
So, what are you waiting for?
Go get some shopping done and walk confidently as you turn heads.
-------------------------------------------
Uomini e Donne: Nilufar porta in esterna Lorenzo? | M.C.G.S - Duration: 4:28.
For more infomation >> Uomini e Donne: Nilufar porta in esterna Lorenzo? | M.C.G.S - Duration: 4:28. -------------------------------------------
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How to replace rear shock absorbers NISSAN X-TRAIL T30 TUTORIAL | AUTODOC - Duration: 11:26.
Use a socket №17 and an open-end wrench №16
Use a socket №17 and a combination spanner №19
Use a socket №14
Using a special tool to compress the spring
Use a socket №17
Before installing new shock absorbers it is strongly recommended to pump them over for 3-5 times manually
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Gemma Galgani shock: "Giorgio ha ammesso di essere ancora innamorato di me" | M.C.G.S - Duration: 2:57.
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Isola dei Famosi: Emma Marrone sbarca in Honduras? Una nuova naufraga dalle iniziali 'E.M.' | - Duration: 4:06.
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담뱃값 인상, 진실된 정부 · 거짓말 하지 않는 대통령을 원한다|조회수4.989.283 - Duration: 13:55.
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#Ex-Chelsea ace Florent Malouda joins club lying in seventh… in Luxembourg league - Duration: 2:31.
Ex-Chelsea ace Florent Malouda joins club lying in seventh… in Luxembourg league
EX-CHELSEA star Florent Malouda has joined a club lying seventh in the league.
in LUXEMBOURG.
The France international won the Champions League, Premier League and three FA Cups before ending his six-year Blues stay in 2013.
Florent Malouda briefly played for the French Guiana national team in 2017.
Malouda, 37, has since played for Trabzonspor, Metz and Delhi Dynamos.
He has now penned a deal with Differdange 03, who have won the Luxembourg title six times - but were last champions of the tiny nation in 1979.
It is a staggering slump in fortunes for the 80-cap winger, who scored 45 goals in 228 Chelsea appearances.
He also played for Chateauroux, Guingamp and Lyon before a £13million move to Stamford Bridge in 2007.
Malouda won the Champions League and the Premier League while at Chelsea.
Midfielder Malouda won 80 caps for France.
However little Differdange are delighted at their transfer coup, and they have invited their entire town to Maloudas presentation tonight [Friday].
A club spokesman said: We have the honour of announcing our new signing, the former Metz and Chelsea player Florent Malouda.
Malouda, 37, had a stint in India playing for the Delhi Dynamos.
He has won the Champions League and the English title, among other trophies.
We invite all of our fans to attend his official news conference, which will be held at 6pm on Friday at the Stade Municipale.
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EJ Carter is Up Next
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Nhạc 3D | Inspired By Alan Walker #1 | 3D Music | 3D version - Duration: 38:49.
Special attention: 3D Music can cause mild hallucinations and addiction
Special attention: 3D Music can cause mild hallucinations and addiction
Special attention: 3D Music can cause mild hallucinations and addiction
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World first $3m Italdesign Zerouno delivery + brutal test drive - Duration: 8:09.
I am at Iconic Cars.
It's a luxury car dealership.
Today it will be the first time I drive a certain car.
Here it is !
wow, wow, wow, a P1.
In black, totally awesome.
and then this wing...
I feel at home in here.
It is similar to my 675LT.
Let's check it out.
The keys.
Where is the START button?
Not here...
Found it!
Wow, that is loud !
Let's put it in RACE mode.
It is very nice with all the carbon fiber.
Race mode not allowed... remaining 1 second... ?
OK, it is in first.
And off I go.
Gorgeous car.
Nice interior with alcantara and carbon fiber.
This car is totally in line with the minimalistic philosophy from Mclaren.
So is there a way to lift the nose?
There is a bump here.
There are always surprises here.
Great cars everywhere.
Mamamia. But I still prefer this one.
I am in the ItalDesign ZeroUno.
Only 5 of these cars are going to be made.
It has an Audi V10 engine
It looks like the R8 V10+
A useful detail, they have a spot for the key.
There is even a button to change the sound.
Ah that's better.
Italdesign is a design studio that exists for over 60 years.
They designed a lot of cars, but this is the first time they make their own car.
They made something different.
The price is around 2,4 million euros.
This is madness.
But it is truly a thing of beauty.
You can sense the spirit of the designer.
it's a true designer car.
A Cobra
The P1
A stunning AMG GT R in white
And, of course, the Pogtador.
I won't complain today.
My favorite among these, is still the P1.
The meter runs backwards
Wow, easily.
No problem.
It's really a modern car. Iit's not a hardcore car.
and it's nice to really enjoy it.
An exceptional car but it gets driven, really driven.
This is how they meant to be used and treated.
So thank you very much Iconiccars in Belgium.
An amazing day, lots of stuff to see.
I had a lot of firsts.
I drove some exceptional cars for the first time.
Definitely awesome.
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Frise chronologique des apprentissages Montessori - Duration: 0:16.
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♦NIGHTCORE♦ Hero - Duration: 2:24.
I'm just a step away
I'm just a breath away
Losin' my faith today
(Fallin' off the edge today)
I am just a man
Not superhuman
(I'm not superhuman)
Someone save me from the hate
It's just another war
Just another family torn
(Falling from my faith today)
Just a step from the edge
Just another day in the world we live
I need a hero to save me now
I need a hero (save me now)
I need a hero to save my life
A hero'll save me (just in time)
I've gotta fight today
To live another day
Speakin' my mind today
(My voice will be heard today)
I've gotta make a stand
But I am just a man
(I'm not superhuman)
My voice will be heard today
It's just another war
Just another family torn
(My voice will be heard today)
It's just another kill
The countdown begins to destroy ourselves
I need a hero to save me now
I need a hero (save me now)
I need a hero to save my life
A hero'll save me (just in time)
I need a hero to save my life
I need a hero just in time
Save me just in time
Save me just in time
Who's gonna fight for what's right
Who's gonna help us survive
We're in the fight of our lives
(And we're not ready to die)
Who's gonna fight for the weak
Who's gonna make 'em believe
I've got a hero (I've got a hero)
Livin' in me
I'm gonna fight for what's right
Today I'm speaking my mind
And if it kills me tonight
(I will be ready to die)
A hero's not afraid to give his life
A hero's gonna save me just in time
I need a hero to save me now
I need a hero (save me now)
I need a hero to save my life
A hero'll save me (just in time)
I need a hero
Who's gonna fight for what's right
Who's gonna help us survive
I need a hero
Who's gonna fight for the weak
Who's gonna make 'em believe
I need a hero
I need a hero
A hero's gonna save me just in time
Autor titulků: Nakamuchi
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♦NIGHTCORE♦ Hero - Duration: 2:24.I'm just a step away
I'm just a breath away
Losin' my faith today
(Fallin' off the edge today)
I am just a man
Not superhuman
(I'm not superhuman)
Someone save me from the hate
It's just another war
Just another family torn
(Falling from my faith today)
Just a step from the edge
Just another day in the world we live
I need a hero to save me now
I need a hero (save me now)
I need a hero to save my life
A hero'll save me (just in time)
I've gotta fight today
To live another day
Speakin' my mind today
(My voice will be heard today)
I've gotta make a stand
But I am just a man
(I'm not superhuman)
My voice will be heard today
It's just another war
Just another family torn
(My voice will be heard today)
It's just another kill
The countdown begins to destroy ourselves
I need a hero to save me now
I need a hero (save me now)
I need a hero to save my life
A hero'll save me (just in time)
I need a hero to save my life
I need a hero just in time
Save me just in time
Save me just in time
Who's gonna fight for what's right
Who's gonna help us survive
We're in the fight of our lives
(And we're not ready to die)
Who's gonna fight for the weak
Who's gonna make 'em believe
I've got a hero (I've got a hero)
Livin' in me
I'm gonna fight for what's right
Today I'm speaking my mind
And if it kills me tonight
(I will be ready to die)
A hero's not afraid to give his life
A hero's gonna save me just in time
I need a hero to save me now
I need a hero (save me now)
I need a hero to save my life
A hero'll save me (just in time)
I need a hero
Who's gonna fight for what's right
Who's gonna help us survive
I need a hero
Who's gonna fight for the weak
Who's gonna make 'em believe
I need a hero
I need a hero
A hero's gonna save me just in time
Autor titulků: Nakamuchi
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